Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Derek B, Rice"'
Publikováno v:
Angewandte Chemie. 134
Publikováno v:
Angewandte Chemie (International ed. in English). 61(41)
The biological process of dinitrogen reduction to ammonium occurs at the cofactors of nitrogenases, the only enzymes that catalyze this challenging chemical reaction. Three types of nitrogenases have been described, named according to the heterometal
Autor:
George E. Cutsail, Rahul Banerjee, Derek B. Rice, Olivia McCubbin Stepanic, John D. Lipscomb, Serena DeBeer
Publikováno v:
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry. 27(6)
Soluble methane monooxygenase (sMMO) facilitates the conversion of methane to methanol at a non-heme FeIV2 intermediate MMOHQ, which is formed in the active site of the sMMO hydroxylase component (MMOH) during the catalytic cycle. Other biological sy
Publikováno v:
Inorganic Chemistry. 58:13902-13916
A combined experimental–computational study of hydrocarbon oxidation by the MnIV-oxo complex of the neutral, pentadentate N4py ligand [N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine] offers s...
Autor:
Timothy A. Jackson, Aruna Munasinghe, Andrew D. Burr, Derek B. Rice, Victor W. Day, Elizabeth N. Grotemeyer
Publikováno v:
Inorganic Chemistry. 58:622-636
Mononuclear MnIII–hydroxo and dinuclear (μ-oxo)dimanganese(III,III) complexes were prepared using derivatives of the pentadentate, amide-containing dpaq ligand (dpaq = 2-[bis(pyridin-2-ylmethyl)]amino-N-quinolin-8-yl-acetamidate). Each of these li
Effect of Lewis Acids on the Structure and Reactivity of a Mononuclear Hydroxomanganese(III) Complex
Publikováno v:
Inorganic chemistry. 59(5)
The addition of Sc(OTf)3 and Al(OTf)3 to the mononuclear MnIII-hydroxo complex [MnIII(OH)(dpaq)]+ (1) gives rise to new intermediates with spectroscopic properties and chemical reactivity distinct from those of [MnIII(OH)(dpaq)]+. The electronic abso
Publikováno v:
Inorganic Chemistry. 57:7825-7837
The solution properties of MnIII-hydroxo and MnIII-methoxy complexes featuring N5 amide-containing ligands were investigated using 1H NMR spectroscopy. The 1H NMR spectrum for one of these complexes, the previously reported [MnIII(OH)(dpaq)](OTf) (dp
Autor:
Hannah E. Colmer, Melissa C. Denler, Victor W. Day, Timothy A. Jackson, Derek B. Rice, Gayan B. Wijeratne
Publikováno v:
Dalton Transactions. 47:13442-13458
The new tetradentate L7BQ ligand (L7BQ = 1,4-di(quinoline-8-yl)-1,4-diazepane) has been synthesized and shown to support MnII and MnIII-peroxo complexes. X-ray crystallography of the [MnII(L7BQ)(OTf)2] complex shows a monomeric MnII center with the L
Publikováno v:
Accounts of Chemical Research. 50:2706-2717
ConspectusBiological systems capitalize on the redox versatility of manganese to perform reactions involving dioxygen and its derivatives superoxide, hydrogen peroxide, and water. The reactions of manganese enzymes influence both human health and the
Publikováno v:
JBIC Journal of Biological Inorganic Chemistry. 22:1281-1293
Mn K-edge X-ray absorption spectroscopy experiments were performed on the solid- and solution-phase samples of [MnII(dpaqR)](OTf) (R=H, Me) and [MnIII(OH)(dpaqR)](OTf). The extended X-ray absorption fine structure (EXAFS) data show distinct differenc