Direct Experimental Observation of in situ Dehydrogenation of an Amine–Borane System Using Gas Electron Diffraction

Autor: João Nunes, Aliyu M. Ja’o, Jean-Claude Guillemin, Derek A. Wann, Sarah L. Masters, Conor D. Rankine

Publikováno v: Journal of Physical Chemistry A
Journal of Physical Chemistry A, American Chemical Society, 2019, 123 (32), pp.7104-7112. ⟨10.1021/acs.jpca.9b05522⟩
Journal of Physical Chemistry A, 2019, 123 (32), pp.7104-7112. ⟨10.1021/acs.jpca.9b05522⟩

International audience; In situ dehydrogenation of azetidine-BH 3 , which is a candidate for hydrogen storage, was observed with the parent and dehydrogenated analogue subjected to rigorous structural and thermochemical investigations. The structural

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::49fa4487e51921b245d674c0f2b9a9b3
https://doi.org/10.1021/acs.jpca.9b05522

Volatile and Thermally Stable Polymeric Tin Trifluoroacetates

Autor: Derek A. Wann, Jason D. Masuda, Goran Bačić, Conor D. Rankine, Seán T. Barry

Publikováno v: Inorganic chemistry. 59(2)

Tin trifluoroacetates are effective vapor phase single-source precursors for F-doped SnO2, but their structures have been poorly understood for decades. Here we undertook a comprehensive structural analysis of these compounds in both the solid and ga

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::002e0ccf9efda08cede10e9701cb9160
https://pubmed.ncbi.nlm.nih.gov/31916436

Competition between Halogen, Hydrogen and Dihydrogen Bonding in Brominated Carboranes

Autor: Drahomír Hnyk, Josef Holub, Jindřich Fanfrlík, Zdeňka Růžičková, Jan Řezáč, Aleš Růžička, Paul D. Lane, Derek A. Wann, Pavel Hobza

Publikováno v: ChemPhysChem. 17:3373-3376

Halogen bonds are a subset of noncovalent interactions with rapidly expanding applications in materials and medicinal chemistry. While halogen bonding is well known in organic compounds, it is new in the field of boron cluster chemistry. We have synt

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e1d5fbf2f3f6a8bf394cfbc539c08327
https://doi.org/10.1002/cphc.201600848

Structure of 4-(Dimethylamino)benzonitrile Using Gas Electron Diffraction: A New Lease of Life for the Only Gas Electron Diffractometer in the U.K

Autor: Tomas W B Lock Feixas, João Nunes, Stuart Young, Conor D. Rankine, Derek A. Wann

Publikováno v: The journal of physical chemistry. A. 122(25)

The continued demand for gas-phase molecular structures has led to the recommissioning of a gas electron diffractometer, formerly housed at the University of Reading. The gas electron diffractometer, now the only one of its kind in the U.K., is curre

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https://pubmed.ncbi.nlm.nih.gov/29870255

Influence of Antipodally Coupled Iodine and Carbon Atoms on the Cage Structure of 9,12-I2-closo-1,2-C2B10H10: An Electron Diffraction and Computational Study

Autor: Norbert W. Mitzel, Raphael J. F. Berger, Josef Holub, Yury V. Vishnevskiy, Drahomír Hnyk, Derek A. Wann, Denis S. Tikhonov, Paul D. Lane, Stuart A. Hayes, Christian G. Reuter

Publikováno v: Inorganic Chemistry. 54:11868-11874

Because of the comparable electron scattering abilities of carbon and boron, the electron diffraction structure of the C2v-symmetric molecule closo-1,2-C2B10H12 (1), one of the building blocks of boron cluster chemistry, is not as accurate as it coul

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8c74be4e17a1f71e10c3da7ad6fed32a
https://doi.org/10.1021/acs.inorgchem.5b02102