Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Denys Baskakov"'
Publikováno v:
Organometallics. 28:5107-5111
New methods for the preparation of NHC-metal complexes have been developed. It was shown that a nitrile group in Reissert analogous compounds can act as a good leaving group in thermal elimination, resulting in carbene formation. Moreover potassium c
Autor:
Denys Baskakov, Wolfgang A. Herrmann
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 283:166-170
Novel water-soluble ligands were prepared in high yields by condensation of various amino acids with tris(hydroxymethyl)phosphane. Rhodium complexes of these ligands, formed in situ, were tested in two-phase hydroformylation of propylene. Selectivity
Publikováno v:
Organometallics. 26:626-632
A chiral C2-symmetric diamine was prepared from (S)-3-phenyl-3,4-dihydroisoquinoline by the virtue of asymmetric transformation. Rhodium and iridium complexes of chiral N-heterocyclic carbenes with restricted flexibility derived from 3,3‘-substitut
Autor:
Tanasri Bunlaksananusorn, Eberhardt Herdtweck, Florian Rampf, Lars Rodefeld, Wolfgang A. Herrmann, Stephan D. Hoffmann, Denys Baskakov
Publikováno v:
Organometallics. 25:2449-2456
New and reliable procedures for the preparation of both enantiomers of 2,2‘-bipiperidine have been developed. Chiral imidazolinium salts derived from 2,2‘-bipiperidine and partially reduced biisoquinoline were prepared in high yields. Rhodium and
Publikováno v:
Journal of Heterocyclic Chemistry. 44:237-239
New C2-symmetric atropisomeric diazepinium salts were prepared utilizing Vilsmeier-Haack activation of corresponding formamide precursors by phosgene solution in toluene. The structures of these substances were verified by X-ray diffraction.
Publikováno v:
Tetrahedron Letters. 45:3023-3025
The fully protected derivatives of the diamino acids lysine and ornithine ( n =1, 2) can be oxidized selectively in the side chain using a Mn(OAc) 2 /peracetic acid/NaOAc system. The e or γ carbon, respectively, is converted to the aldehyde oxidatio
Publikováno v:
ChemInform. 38
New C2-symmetric atropisomeric diazepinium salts were prepared utilizing Vilsmeier-Haack activation of corresponding formamide precursors by phosgene solution in toluene. The structures of these substances were verified by X-ray diffraction.
Carbene Complexes Made Easily: Decomposition of Reissert Compounds and Further Synthetic Approaches.
Publikováno v:
Organometallics; Sep2009, Vol. 28 Issue 17, p5107-5111, 5p
Publikováno v:
Organometallics; Jan2007, Vol. 26 Issue 3, p626-632, 7p