Zobrazeno 1 - 10
of 39
pro vyhledávání: '"Dennis K. Rohrbaugh"'
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 184:2989-2995
Thiocamphor has been found to furnish bornane, camphor, isoborneol, isobornylthiol, bornylthiol, tetrahydro-bis-(1,7,7-trimethylbicyclo[2.2.1]heptyl)-3,3′-disulfide, and three isomeric bis-(1,7,7-trimethylbicyclo[2.2.1]heptyl)-3,3′-dithiols when
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 181:435-445
Reaction of trifluoromethylthiocopper with 1,4-diiodo- and 1-bromo-4-iodocubanes furnishes 1-iodo-4-(trifluoromethylthio)-, 1-bromo-4-(trifluoromethylthio)-, and 1,4-bis(trifluoromethylthio)cubanes in respectable yields (Scheme 1). However, the react
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 179:1645-1655
Vinylsulfides are often obtained via the reaction of substituted acetylenes with sulfur-containing reagents. The presence of other functional groups such as the halide or the hydroxyl moieties enhances the usefulness of the vinylsulfide intermediates
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 179:1657-1671
Trifluoromethylthiocopper has been found to catalyze the opening of the epoxide ring and to furnish not-so-easily accessible novel trifluoromethylthiolated α-hydroxy compounds. This communication presents the mechanism of the formation of the variou
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 177:2471-2479
Seven compounds are formed in various amounts when a solution of cyclopropopyl phenyl propargyl alcohol and trifluoromethylsulfenyl chloride in acetonitrile is exposed to UV light. The probable mechanism of formation and the mass spectral characteriz
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 176:111-118
The thiirane ring cleavage of cyclohexene sulfide with trifluoro-methylthiocopper furnishes seven compounds. Of these, only one compound does not contain the trifluoromethylthio group. This paper presents the probable mechanism of formation of the co
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 159:195-203
connection with another project involving the cleavage of the thiirane ring of cyclohexene episulfide in the presence of trifluoromethylthiocopper, the presence of several unusual cyclic sulfides (5–10, Fig. 1) was observed both in the reaction pro
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 152:65-76
The thermal degradation of mustard gas (ClCH2CH2SCH2CH2Cl, “HD”), with and without 5% added water, is examined. GC/MS, LC/MS and NMR were employed to comprehensively analyze the products. After 75 days at 90°C, 91% HD remains (80% with 5% water)
Publikováno v:
Journal of Fluorine Chemistry. 98:3-9
Based on the mass spectral fragmentation behavior of the reaction products, the free radical reaction of 1-ethynyl-1-cyclopentanol ( 1 ) with trifluoromethylsulfenyl chloride ( 2 ) has been found to furnish 13 compounds formed from addition and elimi
Autor:
Emory W. Sarver, Dennis K. Rohrbaugh
Publikováno v:
Journal of Chromatography A. 809:141-150
A method was developed to detect alkyl methylphosphonic acids in complex matrices using gas chromatography–tandem mass spectrometry. By converting the acids to their trimethylsilyl derivatives and monitoring the collision-induced dissociation of m