Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Dennis A. Buschmann"'
Publikováno v:
Organometallics. 41:962-976
Publikováno v:
Chemical Communications. 58:9132-9135
[Cp*Ln(μ2-Me)2]3 slowly converts into Cp*3Y3(μ2-Me)3(μ3-CH2)(μ3-H)(thf)3 showing selective reactivity towards ketones and full consumption of all bridging ligands with methanol.
Publikováno v:
European Journal of Inorganic Chemistry. 2022
Autor:
Dennis A. Buschmann, David Schneider, Reiner Anwander, Cäcilia Maichle-Mössmer, Damir Barisic
Publikováno v:
Chemistry – A European Journal. 25:4821-4832
Targeting the synthesis of rare-earth-metal pentadienyl half-sandwich tetramethylaluminate complexes, homoleptic [Ln(AlMe4 )3 ] (Ln=Y, La, Ce, Pr, Nd, Lu) were treated with equimolar amounts of the potassium salts K(2,4-dmp) (2,4-dmp=2,4-dimethylpent
Autor:
Verena M. Birkelbach, H. Martin Dietrich, David Schneider, Cäcilia Maichle-Mössmer, Reiner Anwander, Christoph Stuhl, Karl W. Törnroos, Dennis A. Buschmann
Publikováno v:
Chemistry-A European Journal
Chemistry (Weinheim an Der Bergstrasse, Germany)
Chemistry (Weinheim an Der Bergstrasse, Germany)
Tetramethylaluminato/halogenido(X) ligand exchange reactions in half‐sandwich complexes [CpRLa(AlMe4)2] are feasible in non‐coordinating solvents and provide access to large coordination clusters of the type [CpRLaX2]x. Incomplete exchange reacti