Zobrazeno 1 - 10
of 56
pro vyhledávání: '"Dennis, Svatunek"'
Publikováno v:
ACS Omega, Vol 9, Iss 44, Pp 44224-44232 (2024)
Externí odkaz:
https://doaj.org/article/39f64061d67f45d5854da9e41f325c00
Publikováno v:
Accounts of Chemical Research. 55:2467-2479
ConspectusThis Account describes our quest to understand and predict organic reactivity, a principal goal of physical and theoretical organic chemistry. The focus is on the development and testing of models for the prediction of cycloaddition reactiv
Publikováno v:
Journal of the American Chemical Society, vol 144, iss 24
1,2,3-Triazines and 1,2,3,5-tetrazines react rapidly, efficiently, and selectively with amidines to form pyrimidines/1,3,5-triazines, exhibiting an orthogonal reactivity with 1,2,4,5-tetrazine-based conjugation chemistry. Whereas the mechanism of the
Publikováno v:
Chemistry – A European Journal. 29
Publikováno v:
Chemistry – A European Journal. 29
Publikováno v:
Monatshefte für Chemie - Chemical Monthly.
The concise synthesis of a potentially “super-armed” glucuronidation donor is reported. The α-anomer was crystallized and analyzed by single crystal X-ray diffraction. The pyranose ring was found to be in a twist-boat conformation in the solid s
Autor:
Walter Kuba, Barbara Sohr, Patrick Keppel, Dennis Svatunek, Viktoria Humhal, Berthold Stöger, Marion Goldeck, Jonathan C. T. Carlson, Hannes Mikula
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany).
Modified trans-cyclooctenes (TCO) are capable of highly efficient molecular manipulations in biological environments, driven by the bioorthogonal reaction with tetrazines (Tz). The development of click-cleavable TCO has fueled the field of in vivo ch
Autor:
Hannes Mikula, Julia Weber, Dennis Svatunek, Philipp Skrinjar, Gerhard Adam, Rudolf Krska, Christian Hametner, Johannes Fröhlich
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 10, Iss 1, Pp 1129-1134 (2014)
The development of a reliable procedure for the synthesis of the 16-glucoside and 16-sulfate of the resorcylic acid lactone (RAL) type compound zearalenone is presented. Different protective group strategies were considered and applied to enable the
Externí odkaz:
https://doaj.org/article/e22719284d264779af3f611b623eccde
Publikováno v:
Angew Chem Int Ed Engl
Strained cyclic allenes, first discovered in 1966 by Wittig and coworkers, have recently emerged as valuable synthetic building blocks. Previous experimental investigations, and computations reported here, demonstrate that the Diels–Alder reactions
How the Lewis Base F-Catalyzes the 1,3-Dipolar Cycloaddition between Carbon Dioxide and Nitrilimines
Publikováno v:
The Journal of organic chemistry, vol 86, iss 5
Journal of Organic Chemistry, 86(5), 4320–4325. American Chemical Society ({ACS})
Svatunek, D, Hansen, T, Houk, K N & Hamlin, T A 2021, ' How the Lewis Base F-Catalyzes the 1,3-Dipolar Cycloaddition between Carbon Dioxide and Nitrilimines ', The Journal of organic chemistry, vol. 86, no. 5, pp. 4320-4325 . https://doi.org/10.1021/acs.joc.0c02963
The Journal of organic chemistry, 86(5), 4320-4325. American Chemical Society
The Journal of Organic Chemistry
Journal of Organic Chemistry, 86(5), 4320–4325. American Chemical Society ({ACS})
Svatunek, D, Hansen, T, Houk, K N & Hamlin, T A 2021, ' How the Lewis Base F-Catalyzes the 1,3-Dipolar Cycloaddition between Carbon Dioxide and Nitrilimines ', The Journal of organic chemistry, vol. 86, no. 5, pp. 4320-4325 . https://doi.org/10.1021/acs.joc.0c02963
The Journal of organic chemistry, 86(5), 4320-4325. American Chemical Society
The Journal of Organic Chemistry
The mechanism of the Lewis base F- catalyzed 1,3-dipolar cycloaddition between CO2 and nitrilimines is interrogated using DFT calculations. F- activates the nitrilimine, not CO2 as proposed in the literature, and imparts a significant rate enhancemen