Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Denis C. Ouellette"'
Publikováno v:
The Journal of Physical Chemistry. 100:9014-9020
The temperature (T) dependence of the g values for the radiolysis of water with 23 MeV 2H+ and 157 MeV 7Li3+ ion beams is reported. The results indicate that as the linear energy transfer characteristics of the radiation increase, (i) d(g(eaq-))/dT d
Publikováno v:
Canadian Journal of Chemistry. 73:2137-2142
In this publication we report: (i) the rate constants for reaction of the hydrated electron with 1-hexyn-3-ol ((8.6 ± 0.3) × 108 dm3 mol−1 s−1 at 18 °C), cinnamonitrile ((2.3 ± 0.2) × 1010 dm3 mol−1 s−1 at 20 °C), and 1,3-diethyl-2-thio
Autor:
A. John Elliot, Denis C. Ouellette
Publikováno v:
J. Chem. Soc., Faraday Trans.. 90:837-841
The temperature dependence of the rate constant for the reaction, e–aq+ OH → OH–(1) has been measured in liquid water up to 150 °C. The values of k1 were derived from fitting the absorbance vs. time plots of the decay of the hydrated electron
Publikováno v:
Canadian Journal of Chemistry. 68:712-719
The g-values of primary species formed in the γ-radiolysis of water have been estimated for the temperature range 25–300 °C. The g-values for the hydrated electron, the hydroxyl radical, and molecular hydrogen all increase approximately 50% over
Publikováno v:
Fusion Engineering and Design. 13:29-31
The solubilities of hydrogen and oxygen in aqueous solutions containing either 0.5–4.4 mol dm−3 lithium hydroxide, 1.0–5.0 mol dm−3 lithium nitrate, or 2.0 mol dm−3 lithium sulphate are reported for 25 and 70°C and at a partial pressure fo
Publikováno v:
Journal of the Chemical Society, Faraday Transactions. 89:1193
The g values for the primary species formed in the γ-radiolysis of light and heavy water have been measured as a function of temperature up to 300 °C. With the exception of g(H2) and g(D2), all the g values are consistent with the generally accepte
Publikováno v:
International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry. 34:747-751
De-aerated 0.4 mol dm -3 H 2 SO 4 solutions containing either 0.01 mol dm -3 ferrous sulphate or 0.1 mol dm -3 CH 3 OH (or CD 3 OH) were irradiated at room temperature and at 300°C. In the case of CH 3 OH, G(H 2 ) was 4.33 ± 0.22 and 5.10 ± 0.16 a