Výsledky vyhledávání - "Deesha D. Malik"

High-valent first-row transition-metal-oxo complexes are important intermediates in biologically and chemically relevant oxidative transformations of organic molecules and in the water splitting reaction in (artificial) photosynthesis. While high-val

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::cde72cc4bde92a7ef3d7321c0c1fe23e
https://pubmed.ncbi.nlm.nih.gov/36454200

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Formation of cobalt–oxygen intermediates by dioxygen activation at a mononuclear nonheme cobalt(II) center

Autor: Mi Sook Seo, Yong Min Lee, Anirban Chandra, Erik R. Farquhar, Wonwoo Nam, Holger Dau, Kallol Ray, Stefan Mebs, Deesha D. Malik

Publikováno v: Dalton Trans

A mononuclear nonheme cobalt(II) complex, [(TMG(3)tren)Co(II)(OTf)](OTf) (1), activates dioxygen in the presence of hydrogen atom donor substrates, such as tetrahydrofuran and cyclohexene, resulting in the generation of a cobalt(II)-alkylperoxide int

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::429f1a2bad6a01497093fbceed0496ef

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Enhanced Electron-Transfer Reactivity of a Long-Lived Photoexcited State of a Cobalt–Oxygen Complex

Autor: Shunichi Fukuzumi, Wonwoo Nam, Claudio Saracini, Yong Min Lee, Muniyandi Sankaralingam, Deesha D. Malik

Publikováno v: Inorganic Chemistry. 57:10945-10952

Photodynamics and electron-transfer reactivity of an excited state derived from an earth-abundant mononuclear cobalt–oxygen complex ground state, [(TAML)CoIV(O)]2– (1; H4TAML = 3,4,8,9-tetrahydro-3,3,6,6,9,9-hexamethyl-1H-1,4,8,11-benzotetraazo-c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::373a36e68215e441e3772fb668b10e2b
https://doi.org/10.1021/acs.inorgchem.8b01571

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Trapping of a Highly Reactive Oxoiron(IV) Complex in the Catalytic Epoxidation of Olefins by Hydrogen Peroxide

Autor: Katrin Warm, Kallol Ray, Wonwoo Nam, Xenia Engelmann, Erik R. Farquhar, Teresa Corona, Marcel Swart, Deesha D. Malik

Publikováno v: Angewandte Chemie (International ed. in English). 58(12)

The generation of a nonheme oxoiron(IV) intermediate, [(cyclam)FeIV (O)(CH3 CN)]2+ (2; cyclam=1,4,8,11-tetraazacyclotetradecane), is reported in the reactions of [(cyclam)FeII ]2+ with aqueous hydrogen peroxide (H2 O2 ) or a soluble iodosylbenzene (s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bd718003c3824ce7e2dc6aedfd130978
https://pubmed.ncbi.nlm.nih.gov/30663826

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Facile convergent route to indoloquinolines

Autor: Lalitprabha N Salgaonkar, Ketan S. Mandrekar, Hari K. Kadam, Deesha D. Malik, Santosh G. Tilve

A convergent route to indoloquinolines is developed through aldol condensation. This two-step method utilizes commercially available 2-oxoindole and o-nitrobenzaldehyde as starting materials. Chromatography-free method is accomplished for preparing s

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A facile convergent route to indoloquinolines

Autor: Kadam, Hari K., Deesha D. Malik, Lalitprabha Salgaonkar, Ketan Mandrekar, Tilve, Santosh G.

A convergent route to indoloquinolines is developed via Aldol condensation. This two step method utilizes commercially available 2-oxoindole and o-nitrobenzaldehyde as starting materials. Chromatography-free method is accomplished for preparing sever

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