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pro vyhledávání: '"Deepa Rapolu"'
Autor:
Yuhong Fang, Deepa Rapolu, Guoliang Lin, Philip E. Sonnet, Seth B. Herzon, Walden S. Lester, Grant R. Krow
Publikováno v:
The Journal of Organic Chemistry. 68:5292-5299
The reactions of N-(alkoxycarbonyl)-2-azabicyclo[2.2.0]hex-5-enes 5 with halonium ion electrophiles were studied in polar and nonpolar aprotic solvents and also in protic media with the aim of controlling nitrogen neighboring group participation. Spe
Autor:
Guoliang Lin, Deepa Rapolu, Ronald T. Raines, Jingqi Duo, Ilia A. Guzei, Cara L. Jenkins, Grant R. Krow
Publikováno v:
The Journal of organic chemistry. 69(25)
Among the proteinogenic amino acids, only proline is a secondary amine and only proline has a saturated ring. Electronegative substituents on C-4 (that is, C(gamma)) have a substantial effect on the trans/cis ratio of the prolyl peptide bond and the