Zobrazeno 1 - 10
of 53
pro vyhledávání: '"Debabrata Dhara"'
Autor:
Debabrata Dhara, Arumugam Jayaraman, Marcel Härterich, Merle Arrowsmith, Malte Jürgensen, Maximilian Michel, Holger Braunschweig
Publikováno v:
Chemistry – A European Journal.
Autor:
David Scheschkewitz, Cem B. Yildiz, Michael Zimmer, Volker Huch, Ramakirushnan Suriya Narayanan, Kaustubh R. Mote, Pankaj Kalita, Debabrata Dhara, Vadapalli Chandrasekhar, Anukul Jana, Subhadip Mondal
Diphosphene TerMesP = PTerMes (1; TerMes = 2,6-Mes2C6H3; Mes = 2,4,6-Me3C6H2) and NHCMe42 (NHCMe4 = 1,3,4,5-tetramethylimidazol-2-ylidene) exist in an equilibrium mixture with the NHCMe4-coordinated diphosphene 3. While uncoordinated 1 is inert to hy
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bb9c6d2a331e41069ada00a8e8fc1a95
*Yıldız, Cem B. ( Aksaray, Yazar )
We report the reactivity of isolable Au(i)-hydride stabilized by an NHC-coordinated diphosphene towards substrates containing C-C and N-N multiple bonds (NHC = N-heterocyclcic carbene). Reactions with dimethy
We report the reactivity of isolable Au(i)-hydride stabilized by an NHC-coordinated diphosphene towards substrates containing C-C and N-N multiple bonds (NHC = N-heterocyclcic carbene). Reactions with dimethy
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ca6c9c1b03492236515ffd231a493648
Autor:
Debabrata Dhara, Felipe Fantuzzi, Marcel Härterich, Rian D. Dewhurst, Ivo Krummenacher, Merle Arrowsmith, Conor Pranckevicius, Holger Braunschweig
A bulky ferrocenyl-based NHC-stabilised aluminium(iii) dihalide was reduced in different solvents, leading to vastly different outcomes, including formation of a rare example of a dialane and a novel dialuminyl analogue of the Birch reduction.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::daf7e5d6e49ffb9d0f14fbd3d7cafa46
Publikováno v:
Inorganics, Vol 6, Iss 1, p 6 (2017)
Peripherally functionalized low-valent main group species allow for the introduction/interconversion of functional groups without increasing the formal oxidation state of the main group center. Herein, we report a straightforward method for the incor
Externí odkaz:
https://doaj.org/article/8664cfa017754895b7158c02dd05025a
Autor:
Nicolas Chrysochos, U. Deva Priyakumar, Carola Schulzke, Ramapada Dolai, Hemant Kumar Rawat, Holger Braunschweig, Anukul Jana, Vadapalli Chandrasekhar, Ivo Krummenacher, Benedict J. Elvers, Pradeep Kumar Pal, Debabrata Dhara
Publikováno v:
Chemical communications (Cambridge, England). 57(75)
Here we report the synthesis of an N-heterocyclic carbene (NHC)-stabilised phosphinidene oxide by the controlled oxygenation of a phosphinidene under ambient conditions. This compound can be further oxygenated to a phosphinidene dioxide. The stoichio
Autor:
Debabrata Dhara, Shubhajit Das, Swapan K. Pati, David Scheschkewitz, Vadapalli Chandrasekhar, Anukul Jana
Publikováno v:
Angewandte Chemie. 131:15511-15515
Autor:
Swapan K. Pati, Shubhajit Das, David Scheschkewitz, Debabrata Dhara, Anukul Jana, Vadapalli Chandrasekhar
Publikováno v:
Angewandte Chemie International Edition. 58:15367-15371
An NHC-coordinated diphosphene is employed as ligand for the synthesis of a hydrocarbon-soluble monomeric AuI hydride, which readily adds CO2 at room temperature yielding the corresponding AuI formate. The reversible reaction can be expedited by the
Autor:
Sebastian Sobottka, Biprajit Sarkar, Pankaj Kalita, Ramapada Dolai, Debabrata Dhara, Debdeep Mandal, Avijit Maiti, Anukul Jana, Vadapalli Chandrasekhar, Ramakirushnan Suriya Narayanan
Publikováno v:
Chemical Science. 10:4077-4081
The synthesis of organic radicals is challenging due to their inherent instability. In recent years, cyclic(alkyl)(amino)carbene (CAAC)-derived 2-substituted pyrrolinium salts have been used as synthons for the synthesis of isolable carbon-based radi
Autor:
Swapan K. Pati, Vadapalli Chandrasekhar, Anukul Jana, Avijit Maiti, David Scheschkewitz, Pankaj Kalita, Debabrata Dhara, Shubhajit Das
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 49(4)
We report the influence of N-heterocyclic carbenes (NHCs) on the hydrolysis of a diphosphene TerPPTer (1; Ter = 2,6-Mes2C6H3; Mes = 2,4,6-Me3C6H2), a phosphorus-analogue of an alkene. The diphosphene 1 itself is completely inert towards water. Howeve