Zobrazeno 1 - 10
of 89
pro vyhledávání: '"Dean M. Roddick"'
Publikováno v:
Journal of Catalysis. 368:38-52
Chemical-looping dry (CO2) reforming (CLDR) of CH4 over the LaxCe1-x-Fe2O3/Al2O3 (x = 0, 0.33, 0.67, and 1) redox catalysts paves a novel path for efficient syngas production and intensive CO2 reduction. The isolation of CO2 splitting (CS) from parti
Publikováno v:
Dalton Transactions. 47:12420-12430
Syntheses of new asymmetric pincer precursors 1,3-C6H4{CH2P(tBu,X)}2 (tBu,XPCPH; X = Cl, SiMe3, OPh) and a new class of hybrid donor/acceptor pincer ligands 1,3-C6H4{CH2P(tBu,Rf)}2 (tBu,RfPCPH; Rf = CF3, C2F5) are reported. All tBu,XPCPH compounds ar
Publikováno v:
Organometallics. 36:136-141
The protolytic stability of (dfepe)PtMe2 (dfepe = (C2F2)2PCH2CH2P(C2F5)2) and cis-(dfmp)2PtMe2 (dfmp = (C2F5)2PMe) and NMR characterization of their corresponding products in SbF5–HF superacid solvent mixtures are reported. Dissolution of (dfepe)Pt
Autor:
Jeffrey L. Butikofer, Bhusan Thapaliya, Jennifer Phelps, Suman Debnath, Dean M. Roddick, Eric Gale, Navamoney Arulsamy, Courtney L. Vowell
Publikováno v:
Polyhedron. 116:197-203
The synthesis and structural characterization of 2- and 3-coordinate Pt(0) complexes with π-acceptor perfluoroalkylphosphine ligands (PFAP’s) is reported. (dfebp)2Pt (dfebp = (C2F5)2PtBu) was prepared in moderate yield by either thermolysis of (co
Autor:
Dean M. Roddick, Suman Debnath, Sayanti Basu, Jeramie J. Adams, Navamoney Arulsamy, Bradley M. Schmidt
Publikováno v:
Polyhedron. 181:114461
Kinetic and mechanistic studies are presented for the (dfepe)Pt(Me)(NC5F5)+ (dfepe = (C2F5)2PCH2CH2P(C2F5)2) ethylene dimerization catalyst system. New labile complexes (dfepe)PtMe(L)+ (L = NC5F5, C6F5CN, C6F5NH2, C6F5NO2) have been prepared. A gener
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 47(35)
Syntheses of new asymmetric pincer precursors 1,3-C6H4{CH2P(tBu,X)}2 (tBu,XPCPH; X = Cl, SiMe3, OPh) and a new class of hybrid donor/acceptor pincer ligands 1,3-C6H4{CH2P(tBu,Rf)}2 (tBu,RfPCPH; Rf = CF3, C2F5) are reported. All tBu,XPCPH compounds ar
Publikováno v:
Organometallics. 34:4018-4022
Treatment of cis-(dfmp)2PtMe2 (dfmp = (C2F5)2PMe) with the mesitylenium acid (C6Me3H4)+B(C6F5)4– in 1,2-difluorobenzene cleanly produces an unusually stable arene complex, [(η6-C6Me3H3)Pt(dfmp)(CH3...
Publikováno v:
Polyhedron. 84:209-215
The successful isolation and structural characterization of (CF3PCP)Ir(C2H4)2 is reported, which confirms a rare example of axial and equatorial ethylene coordination in a TBP coordination environment. DFT studies indicate a moderate barrier to ethyl
Autor:
Davit Zargarian, Dean M. Roddick
Publikováno v:
Inorganica Chimica Acta. 422:251-264
This review presents a survey of crystallographically characterized pentacoordinate complexes of transition metals from groups 9 (monovalent) and 10 (divalent). Extensive structural analyses of compounds featuring monodentate and terdentate (pincer)
Publikováno v:
Organometallics. 32:6468-6475