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pro vyhledávání: '"David S. Hutchings"'
Autor:
Allan H. White, W.C. Patalinghug, Peter C. Junk, Colin L. Raston, Cameron Jones, Lutz M. Engelhardt, David S. Hutchings
Publikováno v:
J. Chem. Soc., Chem. Commun.. :1560-1562
Monomeric alkyldichloro-antimony(III) and –bismuth(III) compounds [MRCl2], R = C(SiMe3)2C5H4N-2′, and the thermally unstable arsenic(III) analogue are accessible from the appropriate group 15 trichloride and LiR in diethyl ether; treating BiCl3 w
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :973
Cocondensation of calcium, strontium, or barium vapours with excess cot (cyclo-octatetraene) and thf (tetrahydrofuran) affords sparingly thf-soluble, pyrophoric M(cot)(thf)n(1), which decomposes at ca. 60 °C in vacuo to M(cot)(2), M = Ca, Sr, or Ba;