Zobrazeno 1 - 10
of 26
pro vyhledávání: '"David S. Brock"'
Publikováno v:
Chemistry – A European Journal. 28
The NgF 2 ∙MOF 4 (Ng = Kr, Xe; M = Mo, W) and XeF 2 ∙2MOF 4 complexes were synthesized in anhydrous HF (aHF) solvent and melts, respectively. Their single-crystal X-ray diffraction (SCXRD) structures show NgF 2 ∙MOF 4 and XeF 2 ·2MOF 4 have F
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 28(15)
The NgF
Publikováno v:
Chemistry – A European Journal. 25:12105-12119
The noble-gas difluoride adducts, NgF2 ⋅CrOF4 and NgF2 ⋅2CrOF4 (Ng=Kr and Xe), have been synthesized and structurally characterized at low temperatures by Raman spectroscopy and single-crystal X-ray diffraction. The low fluoride ion affinity of C
Publikováno v:
Angewandte Chemie. 129:6347-6350
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 25(52)
The noble-gas difluoride adducts, NgF
Publikováno v:
Journal of the American Chemical Society. 135:5089-5104
The xenon(IV) hydroxide fluoride and oxide fluoride salts, [H(OXeF2)n][AsF6] and [FXe(II)(OXe(IV)F2)n][AsF6] (n = 1, 2), have been synthesized as the natural abundance and the (18)O- and (2)H-enriched salts and structurally characterized by low-tempe
Publikováno v:
Angewandte Chemie (International ed. in English). 56(22)
Examples of coordination compounds in which KrF
A Raman spectroscopic study of the XeOF4/XeF2 system and the X-ray crystal structure of α-XeOF4·XeF2
Publikováno v:
Journal of Fluorine Chemistry. 132:660-668
The mixed oxidation state complexes, α-XeOF 4 ·XeF 2 and β-XeOF 4 ·XeF 2 , result from the interaction of XeF 2 with excess XeOF 4 . The X-ray crystal structure of the more stable α-phase shows that the XeF 2 molecules are symmetrically coordina
Autor:
David S. Brock, Gary J. Schrobilgen
Publikováno v:
Journal of the American Chemical Society. 133:6265-6269
The missing Xe(IV) oxide, XeO(2), has been synthesized at 0 °C by hydrolysis of XeF(4) in water and 2.00 M H(2)SO(4(aq)). Raman spectroscopy and (16/18)O isotopic enrichment studies indicate that XeO(2) possesses an extended structure in which Xe(IV
Publikováno v:
Journal of the American Chemical Society. 132:13823-13839
Xenon fluoride nitrate has been synthesized by reaction of NO(2)F with [FXeOXeFXeF][AsF(6)] at -50 °C. It was characterized in SO(2)ClF and CH(3)CN solutions by low-temperature (14)N, (19)F, and (129)Xe NMR spectroscopy and in the solid state by low