Zobrazeno 1 - 2
of 2
pro vyhledávání: '"David R.J. Hose"'
Publikováno v:
Tetrahedron Letters. 35:5303-5306
The addition of zinc(II)bromide reverses the diastereoselectivity of the diisobutyl-aluminium hydride (DIBAL-H) reduction of benzylidene sulphinamide R (S) R-(−)- 4 . The same reversal is not observed in the reactions of analogues lacking an amide
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c200e136a98a6da4a41931b09879c5e4
https://doi.org/10.1016/s0040-4039(00)77091-2
https://doi.org/10.1016/s0040-4039(00)77091-2
Publikováno v:
Tetrahedron: Asymmetry. 4:2159-2162
The homochiral cyclic sulphinamide S(S)R-(+)-1 has been employed in the asymmetric synthesis of α-methylbenzylamine via the benzylidene sulphinamide R(S)Ri-(−)-3. Following diastereoselective reduction and hydrolysis S(S)R-(+)-1 can be recycled in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6474ed51608b40acdac1a491dfdcbfef
https://doi.org/10.1016/s0957-4166(00)80065-8
https://doi.org/10.1016/s0957-4166(00)80065-8