Zobrazeno 1 - 10
of 294
pro vyhledávání: '"David R, Tyler"'
Autor:
Justin T. Barry, David R. Tyler
Publikováno v:
Inorganic Chemistry. 59:13875-13879
This study measured and compared the combination efficiencies (FcP) of geminate radical cage pairs to nongeminate (collisional) radical cage pairs (Fc′). For the [Cp′(CO)3Mo·, ·Mo(CO)3Cp′] radical ...
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 4, Pp m83-m84 (2015)
The molecule of the title compound, [PtH2(C6H18N3P)2], has a centrosymmetric square-planar structure in which the PtII atom is bonded to two H and two P atoms in a mutually trans configuration. The PtII atom sits on an inversion center and thus the a
Externí odkaz:
https://doaj.org/article/da428b3e6b314182930965f1e26e7f25
Publikováno v:
Journal of Inorganic and Organometallic Polymers and Materials. 30:196-205
The unsymmetrical bidentate phosphine ligands (Me)2PCH2CH2CH2P(Et)2 (14), (Me)2PCH2CH2CH2P(iPr)2 (15), (Me)2PCH2CH2CH2P(Cy)2 (16), and (Me)2PCH2CH2CH2P(Ph)2 (17) were synthesized using air–stable phosphine oxide intermediates. In the first step, so
Publikováno v:
Organometallics. 38:3245-3256
The rational design and synthesis of a novel dialkylbiarylphosphine ligand, 2′-(dimethylphosphine)-2,6-dimethoxy-1,1′-biphenyl (MeSPhos), for palladium-catalyzed C–N cross-coupling reactions is described. Based on previous results, it was hypot
Autor:
David R. Tyler
Publikováno v:
Inorganica Chimica Acta. 485:33-41
Four developments from the author’s laboratory related to doing organometallic and inorganic chemistry in aqueous solution are reviewed. First, the development of new water-soluble cyclopentadienyl ligands and bidentate phosphine ligands is discuss
Publikováno v:
Acta Crystallographica Section E, Vol 70, Iss 1, Pp o5-o5 (2014)
In the title quaternary ammonium salt, C55H61N4+·I−, all three N,N-dibenzylethanamine, –(CH2)2N(CH2C6H5)2, groups have different conformations. The N—C—C—N torsion angles are significantly different [89.86 (13), 162.61 (10) and 175.70 (10)
Externí odkaz:
https://doaj.org/article/f317e4eac992490bbaca79b2da259c50
Publikováno v:
Acta Crystallographica Section E, Vol 68, Iss 12, Pp m1465-m1465 (2012)
The title compound, [RuCl2(C10H14)(C14H15OP)], is an RuII complex in which an η6-p-cymene ligand, two chloride anions and the P atom of an ethoxydiphenylphosphane ligand form a piano-stool coordination environment about the central RuII atom.
Externí odkaz:
https://doaj.org/article/7de53088874546bd85290fd7340565d8
Publikováno v:
Acta Crystallographica Section E, Vol 68, Iss 8, Pp o2456-o2456 (2012)
The title compound, C14H16O4P2·2H2O, possesses a crystallographic inversion center where two –P(=O)(OH)(C6H5) groups are joined together via two –CH2 groups. In the crystal, the acid molecules are linked by the water molecules via O—H...O hydr
Externí odkaz:
https://doaj.org/article/933e104505f74e82a228bd90bb00d961
Publikováno v:
Organometallics. 37:182-190
Although organophosphine syntheses have been known for the better part of a century, the synthesis of phosphines still represents an arduous task for even veteran synthetic chemists. Phosphines as a class of compounds vary greatly in their air sensit
Publikováno v:
Acta Crystallographica Section E, Vol 67, Iss 12, Pp m1808-m1808 (2011)
In the centrosymmetric title compound, [OsCl2(C18H40O4P2)2], the OsII atom adopts a trans-OsCl2P4 geometry, arising from its coordination by two chelating diphosphane ligands and two chloride ions. One of the methoxy side chains of the ligand is diso
Externí odkaz:
https://doaj.org/article/070c89543de7403cb2b909369d1e980a