Zobrazeno 1 - 10
of 219
pro vyhledávání: '"David P. Mills"'
Autor:
Benjamin L. L. Réant, Fraser J. Mackintosh, Gemma K. Gransbury, Carlo Andrea Mattei, Barak Alnami, Benjamin E. Atkinson, Katherine L. Bonham, Jack Baldwin, Ashley J. Wooles, Iñigo J. Vitorica-Yrezabal, Daniel Lee, Nicholas F. Chilton, Stephen T. Liddle, David P. Mills
Publikováno v:
JACS Au, Vol 4, Iss 7, Pp 2695-2711 (2024)
Externí odkaz:
https://doaj.org/article/17d8c09f13904d7197b11b1ac80617b7
Autor:
Ashley J. Wooles, David P. Mills, Floriana Tuna, Eric J. L. McInnes, Gareth T. W. Law, Adam J. Fuller, Felipe Kremer, Mark Ridgway, William Lewis, Laura Gagliardi, Bess Vlaisavljevich, Stephen T. Liddle
Publikováno v:
Nature Communications, Vol 9, Iss 1, Pp 1-11 (2018)
Owing to the propensity for uranium(III) compounds to undergo disproportionation, uranium-element multiple bonds involving uranium(III) oxidation states remain rare. Here the authors report hexauranium-methanediide rings that formally contain uranium
Externí odkaz:
https://doaj.org/article/6d5b982b9054495bbc0c7c6c9cd21250
Autor:
Alasdair Formanuik, Fabrizio Ortu, Iñigo J. Vitorica-Yrezabal, Floriana Tuna, Eric J. L. McInnes, Louise S. Natrajan, David P. Mills
Publikováno v:
Inorganics, Vol 9, Iss 12, p 86 (2021)
Tripodal multidentate ligands have become increasingly popular in f-element chemistry for stabilizing unusual bonding motifs and supporting small molecule activation processes. The steric and electronic effects of ligand donor atom substituents have
Externí odkaz:
https://doaj.org/article/65c9597e519b46c69572de28fa5ab374
Autor:
Matthew Gregson, Erli Lu, David P. Mills, Floriana Tuna, Eric J. L. McInnes, Christoph Hennig, Andreas C. Scheinost, Jonathan McMaster, William Lewis, Alexander J. Blake, Andrew Kerridge, Stephen T. Liddle
Publikováno v:
Nature Communications, Vol 8, Iss 1, Pp 1-11 (2017)
The inverse-trans-influence has been shown to operate in high oxidation state actinide complexes. Here, the authors report tetravalent cerium, uranium and thorium bis(carbene) complexes with trans C=M=C cores where experimental and theoretical data a
Externí odkaz:
https://doaj.org/article/f493a1a8b1374d42be83fd7c35270993
Publikováno v:
Inorganics, Vol 3, Iss 4, Pp 534-553 (2015)
The Ce(III) hydrotris(3,5-dimethylpyrazolyl)borate complex [Ce(TpMe2)2(κ2-dmpz)] (1) (TpMe2 = {HB(dmpz)3}−; dmpz = 3,5-dimethylpyrazolide) was isolated in fair yield from the reaction of [Ce(I)3(THF)4] with two equivalents of [K(TpMe2)] via the fa
Externí odkaz:
https://doaj.org/article/95606ed39deb4f43b96f7e6308ad15d3
Autor:
George Marshall, Ashley J. Wooles, David P. Mills, William Lewis, Alexander J. Blake, Stephen T. Liddle
Publikováno v:
Inorganics, Vol 1, Iss 1, Pp 46-69 (2013)
We report the extension of the series of {BIPMTMSH}− (BIPMR = C{PPh2NR}2, TMS = trimethylsilyl) derived rare earth methanides by the preparation of [Ln(BIPMTMSH)(I)2(THF)] (Ln = Nd, Gd, Tb), 1a–c, in 34–50% crystalline yields via the reaction o
Externí odkaz:
https://doaj.org/article/ec81dd834e834a50a9abc9965abf5a57
Autor:
Hannah M. Nicholas, Conrad A. P. Goodwin, Jon G. C. Kragskow, Selena J. Lockyer, David P. Mills
Publikováno v:
Molecules, Vol 23, Iss 5, p 1138 (2018)
Alkali metal amides are vital reagents in synthetic chemistry and the bis(silyl)amide {N(SiMe3)2} (N′′) is one of the most widely-utilized examples. Given that N′′ has provided landmark complexes, we have investigated synthetic routes to lith
Externí odkaz:
https://doaj.org/article/76dc02dd76f84412b1235d679263b555
Autor:
Matthew Gregson, Erli Lu, David P. Mills, Floriana Tuna, Eric J. L. McInnes, Christoph Hennig, Andreas C. Scheinost, Jonathan McMaster, William Lewis, Alexander J. Blake, Andrew Kerridge, Stephen T. Liddle
Publikováno v:
Nature Communications, Vol 9, Iss 1, Pp 1-1 (2018)
Nature Communications 8: Article number: 14137 (2017); Published: 3 February 2017; Updated: 5 February 2018 The original version of this Article contained a typographical error in Fig. 2, where reagent H2C(Ph2PNSiMe3)2 was incorrectly given as H2C(PN
Externí odkaz:
https://doaj.org/article/1b09eee5f1584179b5f96c140549d8ed
Publikováno v:
Reant, B, Wooles, A, Liddle, S & Mills, D 2023, ' Synthesis and Characterization of Yttrium Methanediide Silanide Complexes ', Inorganic Chemistry, vol. 62, no. 1, pp. 137–146 . https://doi.org/10.1021/acs.inorgchem.2c03053
The salt metathesis reactions of the yttrium methanediide iodide complex [Y(BIPM)(I)(THF)2] (BIPM = {C(PPh2NSiMe3)2}) with the group 1 silanide ligand transfer agents MSiR3 (M = Na, R3 = tBu2Me or tBu3; M = K, R3 = (SiMe3)3) gave the yttrium methaned
Autor:
Benjamin L. L. Réant, Dukula De Alwis Jayasinghe, Ashley J. Wooles, Stephen T. Liddle, David P. Mills
Publikováno v:
Reant, B, De Alwis Jayasinghe, D, Wooles, A J, Mills, D & Liddle, S 2023, ' Comparison of group 4 and thorium M(IV) substituted cyclopentadienyl silanide complexes ', Dalton Transactions . https://doi.org/10.1039/D3DT00987D
We report the synthesis and characterisation of a series of M(IV) substituted cyclopentadienyl hypersilanide complexes of the general formula [M(CpR)2{Si(SiMe3)3}(X)] (M = Hf, Th; CpR = Cp′, {C5H4(SiMe3)} or Cp′′, {C5H3(SiMe3)2-1,3}; X = Cl, C3