Zobrazeno 1 - 10
of 16
pro vyhledávání: '"David N. Primer"'
Autor:
David N. Primer, Kelvin Yong, Antonio Ramirez, Matthew Kreilein, Antonio C. Ferretti, Antonio M. Ruda, Nadia Fleary-Roberts, Jonathan D. Moseley, Siân M. Forsyth, Graham R. Evans, John F. Traverse
Publikováno v:
Organic Process Research & Development. 26:1458-1469
Publikováno v:
ACS Catalysis. 7:7957-7961
A nickel/photoredox, dual-catalyzed amidation reaction between alkylsilicate reagents and alkyl/aryl isocyanates is reported. In contrast to the previously reported reductive coupling process, this protocol is characterized by mild reaction condition
Autor:
John C. Tellis, David N. Primer, Gary A. Molander, Christopher B. Kelly, Matthieu Jouffroy, Niki R. Patel
Publikováno v:
Nature Protocols. 12:472-492
Visible-light-activated photoredox catalysts provide synthetic chemists with the unprecedented capability to harness reactive radicals through discrete, single-electron transfer (SET) events. This protocol describes the synthesis of two transition me
Autor:
Niki R. Patel, David N. Primer, John C. Tellis, Christopher B. Kelly, Matthieu Jouffroy, Gary A. Molander
Publikováno v:
Accounts of Chemical Research
The important role of transition metal-catalyzed cross-coupling in expanding the frontiers of accessible chemical territory is unquestionable. Despite empowering chemists with Herculean capabilities in complex molecule construction, contemporary prot
Publikováno v:
Journal of the American Chemical Society
Single-electron transmetalation is recognized as an enabling technology for the mild transfer of alkyl groups to transition metal catalysts in cross-coupling reactions. Hypercoordinate silicates represent a new and improved class of radical precursor
Publikováno v:
Chemistry - A European Journal. 22:120-123
Novel methods for the incorporation of fluorinated subunits into organic frameworks are important in pharmaceutical, agrochemical, and materials science applications. Herein, the first method for the cross-coupling of benzylic α-trifluoromethylated
Publikováno v:
Journal of the American Chemical Society
The cross-coupling of sp(3)-hybridized organoboron reagents via photoredox/nickel dual catalysis represents a new paradigm of reactivity for engaging alkylmetallic reagents in transition-metal-catalyzed processes. Reported here is an investigation in
Autor:
David N. Primer, Gary A. Molander
The construction of quaternary centers is a common challenge in the synthesis of complex materials and natural products. Current cross-coupling strategies that can be generalized for setting these centers are sparse and, when known, are typically pre
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::98dec531a5f3a21905da2c35675affcb
https://europepmc.org/articles/PMC5605792/
https://europepmc.org/articles/PMC5605792/
Publikováno v:
Science. 345:433-436
A bright outlook for carbon coupling In contemporary organic chemistry, it is straightforward to forge bonds between unsaturated carbons (i.e., carbons already engaged in double bonds) using cross-coupling catalysis. The protocol runs into some troub
Publikováno v:
Chemical Science
A photoredox-catalyzed C–H functionalization of heteroarenes using a variety of primary, secondary, and tertiary alkyltrifluoroborates is reported.
A photoredox-catalyzed C–H functionalization of heteroarenes using a variety of primary, seco
A photoredox-catalyzed C–H functionalization of heteroarenes using a variety of primary, seco