Výsledky vyhledávání - "David J Vandenbroek"

Kinetic Studies on the Reaction of Chlorosulfonyl Isocyanate with Monofluoroalkenes: Experimental Evidence for Both Stepwise and Concerted Mechanisms and a Pre-equilibrium Complex on the Reaction Pathway

Autor: Danielle E. Shipowick, Summer A. Bunting, Jacob C. Milligan, Parker C Horn, Marc C. Perry, Jerry A. Boatz, David J Vandenbroek, Dale F. Shellhamer, Kelli R Hickle, Lincoln B. Smith

Publikováno v: The Journal of Organic Chemistry. 78:246-252

Chlorosulfonyl isocyanate (CSI) is reported to react with hydrocarbon alkenes by a stepwise dipolar pathway to give N-chlorosulfonyl-β-lactams that are readily reduced to β-lactams. Substitution of a vinyl hydrogen for a vinyl fluorine changes the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::62c798d5ee1a64822d69e8c5dc6825c5
https://doi.org/10.1021/jo3016488

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