Zobrazeno 1 - 10
of 25
pro vyhledávání: '"David Grassi"'
Autor:
David Grassi
Publikováno v:
Olimpianos - Journal of Olympic Studies. 6:188-214
Autor:
David Grassi
Publikováno v:
Olimpianos - Journal of Olympic Studies. 6:60-92
Autor:
David Grassi
Publikováno v:
Olimpianos - Journal of Olympic Studies. 6:158-168
Publikováno v:
Olimpianos - Journal of Olympic Studies. 4:37-48
The COVID-19 pandemic has resulted in the decision of the International Olympic Committee (IOC) to postpone the Tokyo 2020 Olympic Games, which is an unprecedented decision that is bringing about colossal challenges to every institutional stakeholder
Publikováno v:
WELFARE E ERGONOMIA. :141-165
Publikováno v:
Chemistry-A European Journal, Vol. 20, No 50 (2014) pp. 16694-16706
An easy and versatile Cu-catalyzed propargylic substitution process is presented. Using easily prepared prochiral dichloro substrates, readily available Grignard reagents together with catalytic amount of copper salt and chiral ligand, we accessed a
Autor:
David Grassi, Alexandre Alexakis
Publikováno v:
CHEMICAL SCIENCE
Chemical Science, Vol. 5, No 10 (2014) pp. 3803-3807
Chemical Science, Vol. 5, No 10 (2014) pp. 3803-3807
The first transition metal-free diastereoselective and enantioselective asymmetric allylic alkylation (AAA) has been disclosed leading to the construction of vicinal tertiary/quaternary centers via a kinetic resolution protocol starting from readily
Autor:
David Grassi, Alexandre Alexakis
Publikováno v:
Angewandte Chemie: International Edition in English, Vol. 52, No 51 (2013) pp. 13642-13646
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
AAA: The asymmetric allylic alkylation (AAA) of trisubstituted cyclic allyl bromides with Grignard reagents is catalytic (2 mol % of ligand) and regioselective (SN 2'/SN 2=91:9→100:0). The quaternary carbon centers are formed with good to high enan
Autor:
Stephen C. Hyde, Janis Veliks, Marc Taillefer, Benoit Liegault, Veronique Gouverneur, David Grassi
Publikováno v:
ChemInform. 47
Copper-catalyzed Si-H, B-H, P-H, S-H, and N-H insertion reactions of 2,2,2-trifluoro-1-diazoethane and 1-aryl 2,2,2-trifluorodiazoethanes generated a large number of new fluorine-containing chemical entities for medicinal chemists. With selected Si-H
Autor:
Alexandre Alexakis, David Grassi
Publikováno v:
ChemInform. 47
Two new N-heterocyclic carbene (NHC) ligands have been synthesized and employed in the transition metal-free asymmetric allylic alkylation (AAA) mediated by Grignard reagents and magnesium alanates. The employment of these ligands showed high yields