Zobrazeno 1 - 6
of 6
pro vyhledávání: '"David G. Bolin"'
Publikováno v:
The Journal of Organic Chemistry. 65:9172-9179
The poly(spirotetrahydrofuranyl)cyclohexanes 1-4 were prepared in a series of steps that began with oxidative demercuration of pentaspirocyclic chloromercurials. Once the resulting alcohols were transformed into their ketones, it proved possible to c
Autor:
Frank G. Riddell, Leo A. Paquette, Marshall Stepanian, David G. Bolin, Sina Sareth, William E. Trego
Publikováno v:
Tetrahedron. 53:7403-7416
Two groups of tetrahydrofuranyl-substituted long-chain carboxylic acids have been prepared under total stereochemical control. The diastereomeric ionophores were subsequently evaluated for their capability of binding alkali metal ions computationally
Publikováno v:
The Journal of Organic Chemistry. 59:2043-2051
The lithiation of (29) and (30) is shown to occur at all three sites with a dissimilar kinetic preference. For the dihydrofuran, reaction at the proton labeled H β' operates predominantly; in the dihydropyran example, H α is the favored site of dep
Publikováno v:
ChemInform. 25
The lithiation of (29) and (30) is shown to occur at all three sites with a dissimilar kinetic preference. For the dihydrofuran, reaction at the proton labeled H β' operates predominantly; in the dihydropyran example, H α is the favored site of dep
Autor:
Marshall Stepanian, William E. Trego, David G. Bolin, Sina Sareth, Leo A. Paquette, Frank G. Riddell
Publikováno v:
ChemInform. 28
Two groups of tetrahydrofuranyl-substituted long-chain carboxylic acids have been prepared under total stereochemical control. The diastereomeric ionophores were subsequently evaluated for their capability of binding alkali metal ions computationally
Publikováno v:
The Journal of organic chemistry. 61(21)
The title alpha-diketone (18) has been synthesized in stereocontrolled fashion. The ability to introduce the four contiguous spirocyclic ether oxygens in extended trans fashion rests on the ability of the Normant reagent (ClMgCH(2)CH(2)CH(2)OMgCl) to