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pro vyhledávání: '"David F. León-Rayo"'
Direct C-H bond functionalization is a useful strategy for the straightforward formation of C-C and C-Heteroatom bonds. In the present work, a unique approach for the challenging electrophilic Au-catalyzed alpha-C-H bond functionalization of tertiary
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d0e3472d38a928a59d314503b1af8177
https://doi.org/10.26434/chemrxiv-2022-l2mlb
https://doi.org/10.26434/chemrxiv-2022-l2mlb
Publikováno v:
Angewandte Chemie (International ed. in English).
Direct C-H bond functionalization is a useful strategy for the straightforward formation of C-C and C-Heteroatom bonds. In the present work, a unique approach for the challenging electrophilic Au-catalyzed α-C-H bond functionalization of tertiary am
Publikováno v:
RSC Advances. 8:24654-24659
A facile and highly efficient method for the bromomethylation of thiols, using paraformaldehyde and HBr/AcOH, has been developed, which advantageously minimizes the generation of highly toxic byproducts. The preparation of 22 structurally diverse α-