Zobrazeno 1 - 6
of 6
pro vyhledávání: '"David Ballweg"'
Autor:
Laura M. Lilley, Sarah Kamper, Michael Caldwell, Zer Keen Chia, David Ballweg, Luke Vistain, Jeffrey Krimmel, Teresa Anne Mills, Keith MacRenaris, Paul Lee, Emily Alexandria Waters, Thomas J. Meade
Publikováno v:
Angewandte Chemie. 132:396-402
Publikováno v:
Journal of the American Chemical Society. 124:12174-12181
Dipotassio-9-germafluorenyl dianion (3b) was synthesized by reduction of 9,9-dichloro-9-germafluorene (4b) with sodium/potassium alloy in tetrahydrofuran. The X-ray crystal structure of 3b, like that for the analogous silicon compound 3a, shows C-C b
Publikováno v:
Silicon Chemistry. 1:55-58
The reaction of spirobisilafluorene (1) with lithium in dimethoxyethane produces lithium 1-methyl-spirobisilafluorenide (2), a stable pentacoordinate silicon compound with five carbon ligands, and lithium 2-methoxyethoxide, which was identified by tr
Publikováno v:
Journal of the American Chemical Society. 124:49-57
1-Silafluorene dianion was synthesized by potassium reduction of 1,1-dichloro-1-silafluorene in refluxing THF. The X-ray structure of 1,1-dipotassio-1-silafluorene (3b) shows C-C bond length equalization in the five-membered silole ring and C-C bond
Publikováno v:
ChemInform. 33
Reductive coupling of aryl aldehydes and ketones is induced by silole and germole dianions at −78 °C in THF, and 1,2-diols are obtained as the only or major products.
Publikováno v:
Organometallics. 20:5769-5770
Reductive coupling of aryl aldehydes and ketones is induced by silole and germole dianions at −78 °C in THF, and 1,2-diols are obtained as the only or major products.