Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Darren K. MacFarland"'
Publikováno v:
Tetrahedron Letters. 47:57-60
A new asymmetric phase-transfer catalyst, designed by combining the chiral building blocks styrene oxide and 2,5-dimethylpyrroline, is described. Catalytic testing using standard glycine imino ester alkylations shows good yields and moderate to good
Publikováno v:
Tetrahedron: Asymmetry. 15:3297-3300
A new asymmetric phase-transfer catalyst is described, along with a new, flexible synthetic scheme using a tartaric acid chloride. Alkylations and Michael reactions on a glycine imino ester show the new catalyst to be an effective phase-transfer cata
Publikováno v:
Tetrahedron: Asymmetry. 15:151-154
Synthesis and characterization of a novel phase-transfer catalyst, 6,6′ di(triethylammoniummethyl)-2,2′-dihexyloxybi-1,1′-naphthalene, are reported. Preliminary catalytic studies on the alkylation of a glycine derivative show the catalyst to be
Autor:
Darren K. MacFarland
Improvements in contrast agents used in Magnetic Resonanace Imaging (MRI), a powerful tool for medical diagnostics, will substantially increase MRI's reach and utility. Targeted imaging agents that highlight diseased areas form avibrant area of labor
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::773e5fa8f0b16275a289d1ea76b036b3
https://doi.org/10.1039/9781849732918-00490
https://doi.org/10.1039/9781849732918-00490
Autor:
Darren K. MacFarland, Kevin A. Walter, Arnold L. Rheingold, Susan E. Kegley, Bruce G. Young, Dirk T. Bergstrom
Publikováno v:
Organometallics. 12:2339-2353
Publikováno v:
ChemInform. 36
A new dicationic asymmetric phase-transfer catalyst, designed by combining chiral elements, is described. Catalytic testing using standard glycine imino ester alkylations shows good yields and moderate enantioselectivities.
Publikováno v:
ChemInform. 36
Herein we report the cleaving of aryl alkyl ethers on BINOL derivatives, using the common reducing agent LAH. The cleavage of the alkyl oxygen bond is observed when the BINOL derivative is treated with LAH, in refluxing dioxane, for 60 h. The resulti
Autor:
Darren K. MacFarland, Clark R. Landis
Publikováno v:
Organometallics. 15:483-485
Novel, chiral, aza-15-crown-5-containing phosphite ligands have been designed, synthesized, and characterized. Metal complexes of these ligands are catalytically active and constitute a starting point for the systematic study of the affect of seconda
Publikováno v:
Journal of Chemical Education. 82:109
An advanced laboratory experiment involving the synthesis of the title compound is described. The suitability of the compound for teaching inert-atmosphere techniques and the stability of the product are discussed. The compound has interesting struct
Publikováno v:
Journal of Chemical Education. 77:1484
A group experiment synthesizing phthalocyanine dyes in one step from commercially available starting materials is described. The importance of a metal template is explored. The experiment is suitable for a second-semester general chemistry course. De