Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Daria Sicinska"'
Publikováno v:
Current Organic Chemistry. 9:75-88
A critical review of applications of chlorine kinetic isotope effects in studies of organic reactions mechanisms is presented. Reports from the last five years are considered. During this time chlorine kinetic isotope effects were applied mainly in s
Publikováno v:
The Journal of Physical Chemistry B. 106:2708-2713
We present a systematic comparison of a cluster model to a continuum solvation model for the rate of decarboxylation of 4-pyridylacetic acid zwitterion. Geometries of the zwitterion and the transition state were optimizedfor the gas-phase reaction, f
Publikováno v:
The Journal of Organic Chemistry. 66:5534-5536
Nitrogen kinetic isotope effects on the decarboxylation of 4-pyridylacetic acid have been measured in solvents of different polarity and have been found to vary from the inverse value of 0.994 to the normal value of 1.002 upon increase of water conte
Autor:
Rafał Kamiński, Łukasz Szatkowski, Tatsuo Kurihara, Juliusz Rudzinski, Renata A. Kwiecień, Nobuyoshi Esaki, Piotr Paneth, Ewa Papajak, Daria Sicinska
Publikováno v:
Biochemistry. 45(19)
dl-2-Haloacid dehalogenase from Pseudomonas sp. 113 is a unique enzyme because it acts on the chiral carbons of both enantiomers, although its amino acid sequence is similar only to that of d-2-haloacid dehalogenase from Pseudomonas putida AJ1 that s
Autor:
Tatsuo Kurihara, Daria Sicinska, Andrzej Lewandowicz, Piotr Paneth, Nobuyoshi Esaki, Susumu Ichiyama, Juliusz Rudzinski
Publikováno v:
Journal of the American Chemical Society. 123(37)
Publikováno v:
Journal of the American Chemical Society. 123(31)
The rate constants and kinetic isotope effects for decarboxylation of 4-pyridylacetic acid depend strongly on whether the solvent is water or dioxane, and the present paper interprets this finding. We calculate the solvent dependence of the free ener