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pro vyhledávání: '"Daniel P. Roek"'
Publikováno v:
Industrial & Engineering Chemistry Research. 39:3090-3096
We report on the solvent effect on a kinetic-controlled energy-transfer reaction in super- and subcritical ethane. The reaction chosen, the quenching of naphthalene fluorescence by C2H5Br, occurs well below the diffusion-controlled limit in liquid so
Autor:
Mary J. Kremer, Daniel P. Roek, John E. Chateauneuf, Christopher B. Roberts, Joan F. Brennecke
Publikováno v:
Fluid Phase Equilibria. :713-722
A number of studies have shown that the local environmental around dissolved solutes in supercritical fluids (SCFs) is significantly different than the bulk. Moreover, in SCF mixtures, there is evidence that the local composition around a dilute solu