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pro vyhledávání: '"Daniel Mulryan"'
In this paper we report a catalytic method to transfer formal equivalents of HF from fluoroalkanes to an alkyne. The method leads to a simple and sustainable approach to generate difluoroalkanes and tolerates numerous sensitive functional groups incl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f631f49b56f45d2cfa6ed78ca69572a5
https://doi.org/10.26434/chemrxiv-2023-lxv28
https://doi.org/10.26434/chemrxiv-2023-lxv28
Publikováno v:
ACS Catalysis. 12:3411-3419
HF transfer reactions between organic substrates are potentially useful transformations. Such reactions require the development of catalytic systems that can promote both defluorination and fluorination steps in a single reaction sequence. Herein, we
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1654d450c39b37324cd28f801c07e5ae
https://doi.org/10.1021/acscatal.1c05474
https://doi.org/10.1021/acscatal.1c05474
HF transfer reactions between organic substrates are an incredibly rare class of transformation. Such reactions require the development of new catalytic systems that can promote both defluorination and fluorination steps in a single reaction sequence
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d0e6bc3c5327644c3573d1a37c700cdf
https://doi.org/10.26434/chemrxiv-2021-72q5b
https://doi.org/10.26434/chemrxiv-2021-72q5b
Publikováno v:
Organic Letters
A new organocatalyzed fluoride metathesis reaction between fluoroarenes and carbonyl derivatives is reported. The reaction exchanges fluoride (F–) and alternate nucleophiles (OAc–, CO2R–, SR–, Cl–, CN–, NCS–). The approach provides a co
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::636bfaa55287a288eb86136eaf7ed9b4
https://doi.org/10.26434/chemrxiv.12901304.v1
https://doi.org/10.26434/chemrxiv.12901304.v1
Publikováno v:
Angewandte Chemie. 130:17135-17140
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::25dced3558233ea3b97dbbfcdcc015f1
https://doi.org/10.1002/ange.201810245
https://doi.org/10.1002/ange.201810245