Výsledky vyhledávání - "Daniel Mulryan"

Catalytic HF Shuttling between Fluoroalkanes and Alkynes

Autor: Daniel Mulryan, Feriel Rekhroukh, Shannon Farley, Mark Crimmin

In this paper we report a catalytic method to transfer formal equivalents of HF from fluoroalkanes to an alkyne. The method leads to a simple and sustainable approach to generate difluoroalkanes and tolerates numerous sensitive functional groups incl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f631f49b56f45d2cfa6ed78ca69572a5
https://doi.org/10.26434/chemrxiv-2023-lxv28

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Au(I) Catalyzed HF Transfer: Tandem Alkyne Hydrofluorination and Perfluoroarene Functionalization

Autor: Daniel Mulryan, Jack Rodwell, Nicholas A. Phillips, Mark R. Crimmin

Publikováno v: ACS Catalysis. 12:3411-3419

HF transfer reactions between organic substrates are potentially useful transformations. Such reactions require the development of catalytic systems that can promote both defluorination and fluorination steps in a single reaction sequence. Herein, we

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1654d450c39b37324cd28f801c07e5ae
https://doi.org/10.1021/acscatal.1c05474

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Au(I) Catalyzed HF Transfer: Tandem Alkyne Hydrofluorination and Perfluoroarene Functionalisation

Autor: Nicholas Phillips, Jack Rodwell, Mark R. Crimmin, Daniel Mulryan

HF transfer reactions between organic substrates are an incredibly rare class of transformation. Such reactions require the development of new catalytic systems that can promote both defluorination and fluorination steps in a single reaction sequence

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d0e6bc3c5327644c3573d1a37c700cdf
https://doi.org/10.26434/chemrxiv-2021-72q5b

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Organocatalyzed Fluoride Metathesis

Autor: Daniel Mulryan, Andrew J. P. White, Mark R. Crimmin

Publikováno v: Organic Letters

A new organocatalyzed fluoride metathesis reaction between fluoroarenes and carbonyl derivatives is reported. The reaction exchanges fluoride (F–) and alternate nucleophiles (OAc–, CO2R–, SR–, Cl–, CN–, NCS–). The approach provides a co

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::636bfaa55287a288eb86136eaf7ed9b4
https://doi.org/10.26434/chemrxiv.12901304.v1

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