Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Daniel Joven-Sancho"'
Autor:
Daniel Joven-Sancho, Luca Demonti, Antonio Martín, Nathalie Saffon-Merceron, Noel Nebra, Miguel Baya, Babil Menjón
Publikováno v:
Chemical Communications. 59:4166-4168
Neutral Ag(III) complexes stabilised with just monodentate ligands are here unambiguously established. In a series of square-planar (CF3)3Ag(L) compounds with hard and soft Group 15 donor ligands, L, the metal center has been found to exhibit substan
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d5f6d903b28335f6098193ee8633daf6
https://doi.org/10.1039/d3cc00493g
https://doi.org/10.1039/d3cc00493g
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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Zaguán. Repositorio Digital de la Universidad de Zaragoza
instname
Zaguán. Repositorio Digital de la Universidad de Zaragoza
By using suitable synthetic procedures, we have first isolated the square-planar organosilver(III) compounds [PPh4][trans-(CF3)2AgX2] [X=Cl (1 a), Br (2 a)]. The geometry and stereochemistry of the chloro-derivative 1 a have been unambiguously establ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2266e21a4f406f0dba449dfd97ff0377
https://doi.org/10.1002/anie.202112449
https://doi.org/10.1002/anie.202112449
Autor:
Jesús Orduna, Daniel Joven-Sancho, Larry R. Falvello, Miguel Baya, Antonio Martín, Babil Menjón
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
instname
The involvement of silver in two-electron AgI/AgIII processes is currently emerging. However, the range of stability of the required and uncommon AgIII species is virtually unknown. Here, the stability of AgIII towards the whole set of halide ligands
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::17a0b4494088ba120fea4e0be07a7008
https://doi.org/10.1002/chem.202101859
https://doi.org/10.1002/chem.202101859
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
instname
Organosilver(III) fluoride complexes have been assigned a key role in different fluorination processes. To the best of our knowledge, however, none of them seem to have been isolated or even detected thus far. Here we report on the successful synthes
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f6217b6191e53073eb0019cd6ce80644
https://doi.org/10.1002/chem.201905771
https://doi.org/10.1002/chem.201905771
Autor:
Miguel Baya, Ma Angeles García-Monforte, Babil Menjón, Irene Ara, Daniel Joven-Sancho, Antonio Martín
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
instname
The improved synthesis of the homoleptic perchlorophenyl stibine (CCl)Sb (1a) has enabled us to obtain detailed spectroscopic and structural information. In contrast to the planar structure shown by the nitrogen homologue (CCl)N, the antimony compoun
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f5ed47e426a9a78bc0efc8f250846f90
https://doi.org/10.1016/j.jorganchem.2019.06.033
https://doi.org/10.1016/j.jorganchem.2019.06.033
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
instname
A comparative study of the homoleptic [M(CF3)4]− complexes of all three coinage metals (M=Cu, Ag, Au) reveals that homolytic M−C bond cleavage is favoured in every case upon excitation in the gas phase (CID‐MS2). Homolysis also occurs in soluti
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f248ff125e0326faf38a33518f0e3c72
https://doi.org/10.1002/ange.201903496
https://doi.org/10.1002/ange.201903496
Autor:
Daniel, Joven-Sancho, Miguel, Baya, Larry R, Falvello, Antonio, Martín, Jesús, Orduna, Babil, Menjón
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
The involvement of silver in two‐electron AgI/AgIII processes is currently emerging. However, the range of stability of the required and uncommon AgIII species is virtually unknown. Here, the stability of AgIII towards the whole set of halide ligan
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::558456b609f3ebe51cd11795c3db15ff
https://pubmed.ncbi.nlm.nih.gov/34190377
https://pubmed.ncbi.nlm.nih.gov/34190377
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
instname
The homoleptic silver(I) compound [PPh4 ][CF3 AgCF3 ] (1) provides a convenient entry to the homoleptic silver(III) derivative [PPh4 ][Ag(CF3 )4 ] (2). Once isolated as pure substances, these compounds exhibit marked thermal stabilities. Their struct
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c44c1dcadc4ef166f89cb225eb6995b
https://doi.org/10.1002/chem.201802960
https://doi.org/10.1002/chem.201802960
Autor:
Miguel Baya, Babil Menjón, Antonio Martín, Jesús Orduna, Larry R. Falvello, Daniel Joven-Sancho
Publikováno v:
Chemistry – A European Journal. 27:12712-12712
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::19055bf68f084bcca548d87d486b4b43
https://doi.org/10.1002/chem.202102873
https://doi.org/10.1002/chem.202102873
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 26(20)
Organosilver(III) fluoride complexes have been assigned a key role in different fluorination processes. To the best of our knowledge, however, none of them seem to have been isolated or even detected thus far. Here we report on the successful synthes
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::e8db1b13a63ac82bb62ecbe445cbd5c0
https://pubmed.ncbi.nlm.nih.gov/31881098
https://pubmed.ncbi.nlm.nih.gov/31881098