Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Daniel J. Mobbs"'
Publikováno v:
Phytochemistry. 52:631-634
The fungus, Mucor plumbeus, has been shown to hydroxylate 9α- and 9β-hydroxy and 9-oxo-2β-methoxyclovane at C-6 and to reduce the 9-ketone stereospecifically to afford the 9β-alcohol.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8348cdd6e6d80e51982f086f7cc43c27
https://doi.org/10.1016/s0031-9422(99)00257-5
https://doi.org/10.1016/s0031-9422(99)00257-5
Publikováno v:
Journal of Chemical Research. 2004:524-526
Daucol 2, 5β, 9α- and 5β, 9β-dihydroxy-(8α-H)-daucane 3 and 5, have been shown to have a fungistatic action against the plant pathogen Botrytis cinerea. The diols were metabolised to 3β, 5β, 9α-trihydroxy-(8α-H)-daucane 7 and 5β, 8α-dihydr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c1a2be13e767c0921649b7e4162b7173
https://doi.org/10.3184/0308234042564009
https://doi.org/10.3184/0308234042564009
Publikováno v:
Journal of Chemical Research. 2004:465-467
The cyclisation of humulene 6,7- and 9,10-epoxides catalysed by methanolic tetracyanoethylene has been examined and the structure of a cyclisation product established by X-ray crystallography.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8be90058778c9972d9049d79fac6fe71
https://doi.org/10.3184/0308234042037293
https://doi.org/10.3184/0308234042037293
Autor:
Daniel J. Mobbs, Antonio J. Macías-Sánchez, Peter B. Hitchcock, Rosario Hernández-Galán, James R. Hanson, Isidro G. Collado, Carlos F. D. Amigo
Publikováno v:
ChemInform. 32
The sesquiterpenoid panasinsane derivatives 11 and 14-16 have been prepared from caryophyllene oxide (7). The novel rearrangement reactions of compounds 11 and 14 under TCNE-catalyzed solvolysis conditions and the reactions of compounds 15 and 16 und
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b61bc10e7132149d5c9f69fed1aebb99
https://doi.org/10.1002/chin.200141204
https://doi.org/10.1002/chin.200141204
Publikováno v:
ChemInform. 37
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::99bab5f0edbdc1d6158dcf631c502cb7
https://doi.org/10.1002/chin.200603172
https://doi.org/10.1002/chin.200603172
Autor:
Peter B. Hitchcock, Antonio J. Macías-Sánchez, James R. Hanson, Daniel J. Mobbs, Isidro G. Collado, Athina Deligeorgopoulou
Publikováno v:
Journal of natural products. 67(5)
The preparation of clovanes 4, 5, 6, 8, and 9, which bear different levels of oxidation on ring C, is described for the first time. The biotransformation of compounds 5, 6, and 9 by the fungus Botrytis cinerea is investigated, yielding compounds 10,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e75a9fb9dafe457d4c06bdb80671e065
https://pubmed.ncbi.nlm.nih.gov/15165139
https://pubmed.ncbi.nlm.nih.gov/15165139
Autor:
Carlos F. D. Amigo, Antonio J. Macías-Sánchez, Peter B. Hitchcock, James R. Hanson, Daniel J. Mobbs, Rosario Hernández-Galán, Isidro G. Collado
Publikováno v:
The Journal of organic chemistry. 66(12)
The sesquiterpenoid panasinsane derivatives 11 and 14-16 have been prepared from caryophyllene oxide (7). The novel rearrangement reactions of compounds 11 and 14 under TCNE-catalyzed solvolysis conditions and the reactions of compounds 15 and 16 und
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cf54c3cc3f9d59756e9822ee775ebf60
https://pubmed.ncbi.nlm.nih.gov/11397171
https://pubmed.ncbi.nlm.nih.gov/11397171
Publikováno v:
Journal of natural products. 61(11)
The metabolism of the fungistatic agent 2beta-methoxyclovan-9alpha-ol (2) by the fungus Botrytis cinerea has been investigated. Biotransformation of compound 2 yielded compounds 3-5, 7, and 9. The major metabolites of compound 2 each show much reduce
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6b3b91028209786fe04abb0043ea8c37
https://pubmed.ncbi.nlm.nih.gov/9834150
https://pubmed.ncbi.nlm.nih.gov/9834150
Autor:
Daniel J. Mobbs, James R. Hanson
Publikováno v:
Journal of Chemical Research. 2004:522-523
An intramolecular hydrogen transfer from the chloroacetoxy group has been shown to occur in the hydrolysis of the sesquiterpenoid derivative, 5β-chloroacetoxy-15-norpanasinsan-8-one leading to the formation of 5ββ,8α-dihydroxy-15-norpanasinsane.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::41c55d27d24382cf08f4b7d637bc9d26
https://doi.org/10.3184/0308234042563983
https://doi.org/10.3184/0308234042563983