Trapping of an Heterometallic Unsaturated Hydride: Structure and Properties of the Ammonia Complex [MoMnCp(μ-H)(μ-PPh2)(CO)5(NH3)]

Autor: M. Angeles Alvarez, Daniel García-Vivó, Estefanía Huergo, Miguel A. Ruiz

Publikováno v: Inorganics, Vol 6, Iss 4, p 125 (2018)

Complexes displaying multiple bonds between different metal atoms have considerable synthetic potential because of the combination of the high electronic and coordinative unsaturation associated to multiple bonds with the intrinsic polarity of hetero

Externí odkaz: https://doaj.org/article/fa816413c3f34918a8fc33f1679214db

Chemistry of a Nitrosyl Ligand κ:η-Bridging a Ditungsten Center: Rearrangement and N-O Bond Cleavage Reactions

Autor: M. Angeles Alvarez, M. Esther García, Daniel García-Vivó, Ana M. Guerra, Miguel A. Ruiz, Larry R. Falvello

Publikováno v: Scopus

The novel nitrosyl-bridged complex [W2Cp2(μ-PtBu2)(μ-κ:η-NO)(CO)(NO)](BAr4) [Ar = 3,5-C6H3(CF3)2] was prepared in a multistep procedure starting from the hydride [W2Cp2(μ-H)(μ-PtBu2)(CO)4] and involving the new complexes [W2Cp2(μ-PtBu2)(CO)4](

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e4bb14229ba4488fb4f0f13490907fa8
https://pubmed.ncbi.nlm.nih.gov/36106823

Reactivity of N-Phosphinoguanidines of the Formula (HNR)(Ph2PNR)C(NAr) toward Main Group Metal Alkyls: Facile Ligand Rearrangement from N-Phosphinoguanidinates to Phosphinimine-Amidinates

Autor: Fernando Carrillo-Hermosilla, Antonio Rodríguez-Diéguez, Daniel García-Vivó, Rafael Fernández-Galán, Estefanía Huergo, Alberto Ramos, Antonio Antiñolo

Publikováno v: Inorganic Chemistry. 59:15262-15275

We report the reactivity of N-phosphinoguanidines of the formula (HNR)(Ph2PNR)C(NAr) (R = iPr and Ar = 2,6-iPr2C6H3 [Dipp] for 1a, R = iPr and Ar = 2,4,6-Me3C6H2 [Mes] for 1b, and R = Cy and Ar = D...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::50fb696ab9594d059f15ba97cc9edf38
https://doi.org/10.1021/acs.inorgchem.0c02224

ZnEt2 as a precatalyst for the addition of alcohols to carbodiimides

Autor: Antonio Antiñolo, Daniel García Vivó, FERNANDO CARRILLO-HERMOSILLA, Alberto Ramos, Rafael Fernández-Galán, Jesús Naranjo Rodríguez, David Elorriaga

Publikováno v: Scopus

MCIN/AEI [PID2020-117353GB-I00, PGC2018-097366-B-I00, RED2018-102387-T]; Junta de Comunidades de Castilla-La Mancha & ERDF, EU [2021-AYUDA-32015]

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2a19c89dfa56824ee7a009de645c60a2
http://hdl.handle.net/10651/67672

One-step synthesis and P–H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives

Autor: Miguel A. Ruiz, Patricia Vega, M. Esther García, M. Angeles Alvarez, Daniel García-Vivó, Mónica Burgos

Publikováno v: Scopus
RUO: Repositorio Institucional de la Universidad de Oviedo
Universidad de Oviedo (UNIOVI)
RUO. Repositorio Institucional de la Universidad de Oviedo
instname

Photolysis of [Mo2Cp2(CO)6] and PH2R* (R* = 2,4,6-C6H2tBu3) yielded the title complex, which turned out to be a versatile precursor of novel heterometallic phosphinidene-bridged complexes via three different P–H bond activation processes: photolysi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e70d97b3d77daadbca246b3da96764f9
https://doi.org/10.1039/c9dt02382h