Zobrazeno 1 - 10
of 134
pro vyhledávání: '"Daniel E. Falvey"'
Autor:
Nikolaos Liaros, Sandra A. Gutierrez Razo, Matthew D. Thum, Hannah M. Ogden, Andrea N. Zeppuhar, Steven Wolf, Tommaso Baldacchini, Matthew J. Kelley, John S. Petersen, Daniel E. Falvey, Amy S. Mullin, John T. Fourkas
Publikováno v:
iScience, Vol 25, Iss 1, Pp 103600- (2022)
Summary: We introduce techniques for probing the dynamics of triplet states. We employ these tools, along with conventional techniques, to develop a detailed understanding of a complex chemical system: a negative-tone, radical photoresist for multiph
Externí odkaz:
https://doaj.org/article/d163417ba98545e7822f24570ad315d7
Autor:
Daniel E. Falvey
Publikováno v:
ACS Omega, Vol 3, Iss 8, Pp 10418-10432 (2018)
Externí odkaz:
https://doaj.org/article/a12acd0df9ea4a94bc7fc327b218df32
Autor:
Edward S. Chinn, Daniel E. Falvey
Publikováno v:
Photochemical & Photobiological Sciences. 21:1907-1914
A photochemical precursor to the 5-endo-10,11-dihydroazepine nitrenium ion (1) was synthesized and used to characterize the intermediate by laser flash photolysis and stable product analysis. In addition, DFT calculations were carried out on the nitr
Publikováno v:
Photochemistry and Photobiology. 97:1335-1342
The solvent is an important, yet often forgotten part of a reaction mechanism. Many photochemical polymerizations are carried out using dimethyl sulfoxide (DMSO) as a way to promote the solubility of both the reactants and products, but its reactivit
Autor:
Andrea N. Zeppuhar, Daniel E. Falvey
Publikováno v:
The Journal of Organic Chemistry. 85:8844-8850
The behavior of the N,N-di(4-bromophenyl)nitrenium ion under acidic aqueous conditions was examined via laser flash photolysis experiments. A long-lived species forms and can be assigned as the cation radical or the dication. This species is unreacti
Publikováno v:
The Journal of Physical Chemistry A. 124:4211-4222
The rise in popularity of photochemically initiated reversible addition-fragmentation chain transfer (RAFT) polymerization (photoRAFT) along with the broad spectrum of proposed, and possible, initiation mechanisms result in the need for careful chara
Autor:
Nikolaos Liaros, Sandra A. Gutierrez Razo, Matthew D. Thum, Hannah M. Ogden, Andrea N. Zeppuhar, Steven Wolf, Tommaso Baldacchini, Matthew J. Kelley, John S. Petersen, Daniel E. Falvey, Amy S. Mullin, John T. Fourkas
Publikováno v:
iScience, Vol 25, Iss 1, Pp 103600-(2022)
iScience
iScience
Summary We introduce techniques for probing the dynamics of triplet states. We employ these tools, along with conventional techniques, to develop a detailed understanding of a complex chemical system: a negative-tone, radical photoresist for multipho
Publikováno v:
Photochemical & Photobiological Sciences. 18:1990-1995
The 9-phenyl-9-tritylone photoremovable protecting group was examined using both photoproduct analysis and laser flash photolysis in order to determine the details of its mechanism of alcohol release. It is shown that formation of the tritylone anion
Autor:
Andrea N, Zeppuhar, Daniel E, Falvey
Publikováno v:
The Journal of organic chemistry. 85(14)
The behavior of the
Autor:
Daniel E. Falvey, Andrea N. Zeppuhar
The behavior of the N,N-di(4-bromophenyl)nitrenium ion under acidic aqueous conditions was examined via laser flash photolysis experiments. A long-lived species forms and can be assigned as the cation radical or the dication. This species is unreacti
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::16824de33e17a30fa5aebb8f2d1dbe4c
https://doi.org/10.26434/chemrxiv.11958969.v1
https://doi.org/10.26434/chemrxiv.11958969.v1