Direct reaction of photogenerated diarylcarbenes at square-planar rhodium(i)

Autor: Simon B. Duckett, Danièle Schott, María-Dolores Gálvez-López, Robin N. Perutz

Publikováno v: Dalton Trans.. :2746-2749

A series of carbene complexes RhCl(CR′2)(PR3)2 (R = Ph, Tol, Me, R′ = Ph and Tol) have been synthesised through direct reaction of photochemically generated free diarylcarbene with RhCl(CO)(PR3)2. This route to carbene complexes demonstrates the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c737acdbfdde5fefc3be1a2473faadf0
https://doi.org/10.1039/b407735k

The reaction of M(CO) 3 (Ph 2 PCH 2 CH 2 PPh 2 ) (M = Fe, Ru) with parahydrogen: probing the electronic structure of reaction intermediates and the internal rearrangement mechanism for the dihydride products

Autor: Robin N. Perutz, Jose M. Goicoechea, Jeremy N. Harvey, Cyril Godard, John P. Dunne, Roger J. Mawby, Philip Callaghan, Michael K. Whittlesey, Georg Müller, John P. Lowe, Simon B. Duckett, Danièle Schott, Rinaldo Poli

Publikováno v: Dalton Transactions
Dalton Transactions, 2004, 20, pp.3218-3224. ⟨10.1039/B407457B⟩
Dalton Transactions, Royal Society of Chemistry, 2004, pp.3218-3224. ⟨10.1039/B407457B⟩

The photochemical reaction of Ru(CO)(3)(dppe) and Fe(CO)(3)(dppe)(dppe = Ph(2)PCH(2)CH(2)PPh(2)) with parahydrogen has been studied by in situ-photochemistry resulting in NMR spectra of Ru(CO)(2)(dppe)(H)(2) that show significant enhancement of the h

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6b866e90af419e592fc5a314883611da
https://hal.science/hal-03278472/file/196-10.1039-B407457B-Accepted.pdf

The reaction of M(CO)3(Ph2PCH2CH2PPh2) (M = Fe, Ru) with parahydrogen: probing the electronic structure of reaction intermediates and the internal rearrangement mechanism for the dihydride products.

Autor: Danièle Schott, Philip Callaghan, John Dunne, Simon B. Duckett, Cyril Godard, José M. Goicoechea, Jeremy N. Harvey, John. P. Lowe, Roger J. Mawby, Georg Müller, Robin N. Perutz, Rinaldo Poli, Michael K. Whittlesey

Publikováno v: Dalton Transactions: An International Journal of Inorganic Chemistry; Oct2004, Vol. 2004 Issue 20, p3218-3224, 7p