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A cavity-shaped cis-chelating P,N ligand for highly selective nickel-catalysed ethylene dimerisation
Autor:
Yang Li, Katrin Pelzer, Damien Sechet, Geordie Creste, Dominique Matt, Pierre Braunstein, Dominique Armspach
Publikováno v:
Dalton Transactions. 51:11226-11230
The presence of a cyclodextrin cavity in a chelating P,N ligand promotes the exclusive formation of 1 : 1 ligand/metal complexes. A Ni(ii) complex of the ligand is a very selective catalyst for ethylene dimerisation as a result of metal confinement.
Autor:
Yang, Li, Katrin, Pelzer, Damien, Sechet, Geordie, Creste, Dominique, Matt, Pierre, Braunstein, Dominique, Armspach
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 51(30)
The presence of a permethylated α-cyclodextrin (α-CD) cavity in a chelating P,N ligand promotes exclusive formation of 1 : 1 ligand/metal complexes. In MX