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pro vyhledávání: '"Daizy M. De La Torre"'
Autor:
Daizy M. De La Torre, Joseph Derosa, Zhen Liu, Mark N. Boulous, Joshua L. Turnbull, Miriam L. O’Duill, Keary M. Engle, Annabelle L. Cantu
Publikováno v:
Journal of the American Chemical Society. 139:5183-5193
A regioselective anti-hydrochlorination of unactivated alkynes is reported. The reaction utilizes in situ generated HCl as the source of both the Cl– and H+ and is catalyzed by palladium(II) acetate, with loadings as low as 25 ppm. Removable picoli