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pro vyhledávání: '"Dah-yu Kao"'
Autor:
Dah-Yu Kao, 高大宇
92
The monomer-dimer self-association of some alcohols with bulky side chains has been studied using FTIR spectroscopy. The spectral band of the OH fundamental stretching for a monomer and that for a dimer were resolved and their respective inte
The monomer-dimer self-association of some alcohols with bulky side chains has been studied using FTIR spectroscopy. The spectral band of the OH fundamental stretching for a monomer and that for a dimer were resolved and their respective inte
Externí odkaz:
http://ndltd.ncl.edu.tw/handle/67780504842471540172
Publikováno v:
Journal of the Chinese Chemical Society. 64:1156-1163
The monomer–dimer self-association of the dilute 3-ethyl-2-methyl-3-pentanol in tetrachloroethylene in the very dilute state was studied by infrared spectroscopy at several temperatures. The solute was deliberately chosen so that higher oligomers w
Publikováno v:
Journal of Nuclear Science and Technology. 53:921-927
The amount of total organic carbon (TOC) leached from cation exchange resins (CERs) in condensate demineralizers are related to the quality of reactor water in nuclear power plants (NPPs). In the recent years, quality problems of CERs used by ChinSha
Publikováno v:
Journal of Solution Chemistry. 42:2269-2280
The monomer–dimer self-association equilibrium of 2,2-dimethyl-3-ethyl-3-pentanol in n-octane has been studied by IR spectroscopy at four temperatures (288, 298, 308, and 318 K). The solute was chosen to restrict the self-association between solute
Publikováno v:
Journal of the Chinese Chemical Society. 52:1171-1178
Two equations of linear type (Eqs. 10 and 17 in the text) have been derived to analyze the IR data to determine the dimerization constant consistently. Equation 10 is to be used to fit the integrated absorbances of the monomer band to obtain the mola
Autor:
Dah-Yu Kao, Jenn-Shing Chen
Publikováno v:
Journal of the Chinese Chemical Society. 51:881-888
The monomer-dimer self-association of 3-ethyl-2-methyl-pentanol in CCl4 at four different temperatures has been studied using IR spectroscopy. The spectral band of the OH fundamental stretching for a free monomer and that for a hydrogen-bonded dimer
Publikováno v:
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 60:2287-2293
The dimerization of 2,2-dimethyl-3-ethyl-3-pentanol in tetrachloroethylene in the diluted region has been studied at four temperatures by IR spectroscopy. The aforementioned solute compound is chosen because self-association beyond dimerization is ha
Autor:
Dah-Yu Kao, Jenn-Shing Chen
Publikováno v:
Zeitschrift für Physikalische Chemie. 218:231-244
Two new equations have been derived to treat the IR data from the monomer-dimer self-association. Equation (9), in the text, is to regress the integrated absorbances of the monomer bands to determine the molar absorptivity of the monomer band, ε m,
Publikováno v:
Journal of Solution Chemistry. 26:817-832
We describe a novel graphical method which, in conjunction with the previously proposed graphical determination of monomer shift, dimer shift, and dimerization constant for self-association, allows us to determine the complex shift and equilibrium co