Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Dagmara A. Ortmann"'
Publikováno v:
Organometallics. 21:2369-2381
The mixed-ligand complex [IrCl(C2H4)(SbiPr3)(PiPr3)] (2), prepared from [IrCl(C2H4)(PiPr3)]2 (1) and SbiPr3, reacts not only with CO, diphenylacetylene, and H2 by ligand substitution or oxidative addition but also with diaryldiazomethanes R2CN2 to gi
Publikováno v:
Organometallics. 20:1776-1782
In contrast to trans-[IrCl(C2H4)(SbiPr3)2] (2), which has been obtained from [IrCl(C2H4)2(SbiPr3)2] (1) by abstraction of ethene together with some byproducts, the corresponding cycloocteneiridium(...
Publikováno v:
Chemische Berichte. 129:411-417
The reaction of [IrCl(C8H14)2]2 (2) with SbiPr3 in the presence of H2 yields the dihydridoiridium(III) complex cis,mer-[IrH2Cl(SbiPr3)3] (3) which on treatment with CO and with HCCR (R = Ph, CO2Me) affords the octahedral derivatives [IrH2Cl(CO)(SbiPr
Publikováno v:
Organometallics. 18:952-954
Using the mixed phosphine−stibine compound [IrCl(C2H4)(PiPr3)(SbiPr3)] (2) as the starting material, the square-planar carbeneiridium(I) complexes [IrCl(CR2)(PiPr3)(SbiPr3)] (3a,b) and trans-[IrCl(CR2)(PiPr3)2] (4a,b) were prepared. The cyclopentad