Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Dae-Yeun Kim"'
Publikováno v:
Synthetic Communications. 26:3225-3235
Allylic substitution of allylic cyclic carbonates with PhSH or PhOH in the presence of CpRu(PPh3)2Cl (5 mol %) afforded (E)-allylic alcohol and erythro-β-hydroxy thiophenoxide or phenoxide respectively, via external attack of nucleophiles to π-ally
Publikováno v:
Synthetic Communications. 26:1493-1498
Allylation of aldehydes by reaction allylic phosphates with diethylzinc in the presence of Pd(PPh3)4 afforded homoallylic alcohol via nucleophilic allylzinc species.
Publikováno v:
Synthetic Communications. 26:1485-1492
RuH2(PPh3)4-catalyzed reductive cleavage reactions of chiral allylic cyclic carbonates with ammonium formate afforded optically active (E)-allylic alcohols with excellent regioselectivity. Alternatively, hydrogenolysis of propargylic cyclic carbonate
Publikováno v:
ChemInform. 25
Reaction of chiral dienylic cyclic carbonates with dialkylcopper-magnesium complex R2CuMgX (RMgX: CuI=2: 1)BF3·OEt2 in THF at −78 °C for 30 min afforded γ-alkylated (E)-allylic alcohols with excellent regioselectivity and diastereoselectivity.
Publikováno v:
ChemInform. 27
RuH2(PPh3)4-catalyzed reductive cleavage reactions of chiral allylic cyclic carbonates with ammonium formate afforded optically active (E)-allylic alcohols with excellent regioselectivity. Alternatively, hydrogenolysis of propargylic cyclic carbonate
Publikováno v:
ChemInform. 27
Allylation of aldehydes by reaction allylic phosphates with diethylzinc in the presence of Pd(PPh3)4 afforded homoallylic alcohol via nucleophilic allylzinc species.
Publikováno v:
ChemInform. 27
Allylic substitution of allylic cyclic carbonates with PhSH or PhOH in the presence of CpRu(PPh3)2Cl (5 mol %) afforded (E)-allylic alcohol and erythro-β-hydroxy thiophenoxide or phenoxide respectively, via external attack of nucleophiles to π-ally
Publikováno v:
Tetrahedron: Asymmetry. 5:21-22
Reaction of chiral dienylic cyclic carbonates with dialkylcopper-magnesium complex R2CuMgX (RMgX: CuI=2: 1)BF3·OEt2 in THF at −78 °C for 30 min afforded γ-alkylated (E)-allylic alcohols with excellent regioselectivity and diastereoselectivity.
Publikováno v:
Synthetic Communications; Sep1996, Vol. 26 Issue 17, p3225-3235, 11p
Publikováno v:
Synthetic Communications; Apr1996, Vol. 26 Issue 8, p1493-1498, 6p