Zobrazeno 1 - 10
of 222
pro vyhledávání: '"DAVID R. McMILLIN"'
Autor:
David R. McMillin
Publikováno v:
Journal of Chemical Education. 98:2912-2918
Atoms may repel or attract each other, but bound systems get virtually all of the attention in the classroom. To address the imbalance, instructors can explore the basis of repulsion in a few simple systems and highlight the important role played by
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::65d7c3572f9bcfc50166d44009e6a8c9
https://doi.org/10.1021/acs.jchemed.1c00326
https://doi.org/10.1021/acs.jchemed.1c00326
Autor:
David R. McMillin
Publikováno v:
Journal of Chemical Education. 97:3652-3657
In multielectron atoms or molecules, quantized electronic energy states known as term states provide a framework for interpreting absorption and emission spectra. Enumerating the term states associ...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4739710092d18fb21bc392c91656e9f3
https://doi.org/10.1021/acs.jchemed.0c00243
https://doi.org/10.1021/acs.jchemed.0c00243
Autor:
David R. McMillin, Chia-Rui Shen, William B. Connick, Jeanette A. Krause, Norman Lu, Nathaniel M. Barker, Shih-Sheng Sun, Mandy M. Lee, Yu-Xuan Li
Publikováno v:
Inorganic Chemistry. 58:10716-10724
PtI2(5,5'-bis(HCF2CH2OCH2)-2,2'-bpy)], 55-2FH-PtI2, is the first example of a substituted fluorinated diiodoplatinum diimine complex that exhibits polymorphism. The complex, upon recrystallization, forms two different polymorphs, denoted as α and β
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b22f995aedd0605f6b2f8881ba43163d
https://doi.org/10.1021/acs.inorgchem.9b00669
https://doi.org/10.1021/acs.inorgchem.9b00669
Autor:
David R. McMillin
Publikováno v:
Journal of Chemical Education. 95:1587-1591
The Pauli exclusion principle is a key postulate of the quantum theory and informs much of what we know about matter. In terms of electronic structure, the lone, deceptively simple mathematical requirement is that the total wave function be antisymme
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3083bf588b2d3e8d97b90a0d19dd7eff
https://doi.org/10.1021/acs.jchemed.8b00407
https://doi.org/10.1021/acs.jchemed.8b00407
Publikováno v:
Inorganic Chemistry. 57:6521-6529
This report describes the synthesis and characterization of a series of eight [Pt(NNN)X]+ complexes where the tridentate NNN ligand is (2,2′-bipyrid-6-yl)(pyrid-2-yl)sulfide (btp) or methyl(2,2′-bipyrid-6-yl)(pyrid-2-yl)amine (bmap) and X is OMe,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::803124024e32581d98a619ede2534e3f
https://doi.org/10.1021/acs.inorgchem.8b00636
https://doi.org/10.1021/acs.inorgchem.8b00636
Autor:
Sean N. Natoli, David R. McMillin
Publikováno v:
Journal of Chemical Education. 95:126-130
Students collect magnetic susceptibility data to verify that Hund’s rule correctly predicts electronic configurations. Systems examined include three commercially available lanthanide(III)-containing complexes of the form M(acac)3(H2O)2 (where M =
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8a05613ba65b137d80d4af5d96744a64
https://doi.org/10.1021/acs.jchemed.7b00357
https://doi.org/10.1021/acs.jchemed.7b00357
Autor:
Kothanda Rama Pichaandi, Paul R. Sharp, David R. McMillin, Lakshmi Nilakantan, Mahdi M. Abu-Omar
Publikováno v:
Journal of Organometallic Chemistry. 844:30-34
We report here the synthesis of bis(DEDT –S,S)-μ-(naphthyl-1,8) digold(II) (1) (DEDT = diethyldithiocarbamate) with a formal Au-Au bond. Complex 1 is formed from the reaction of Au(DEDT)Cl2 with 1,8-dilithioaphthalene, a unique synthesis as gold(I
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::749b5caeb6218c3ce8d68a2a80353fba
https://doi.org/10.1016/j.jorganchem.2017.04.032
https://doi.org/10.1016/j.jorganchem.2017.04.032
Autor:
Eileen C. Judkins, David R. McMillin, Dmitry Morozov, Lyudmila V. Slipchenko, Carlos H. Borca, Sarah F. Tyler
Publikováno v:
Journal of Chemical Education. 94:1232-1237
Electronic spectra often exhibit vibronic structure when vibrational and electronic transitions occur in concert. Theory reveals (1) that orbital symmetry considerations determine specific roles played by the nuclear degrees of freedom and (2) that t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cb0ec0a7a5b1bb26cc62cccdc1906517
https://doi.org/10.1021/acs.jchemed.7b00289
https://doi.org/10.1021/acs.jchemed.7b00289
Autor:
Matthias Zeller, Sean M. Ryno, Jianguo Mei, Saadia T. Chaudhry, Chad Risko, David R. McMillin
Publikováno v:
The journal of physical chemistry. B. 123(17)
The oxidation pathways and products of a discrete, sulfide-endcapped donor–acceptor–donor (D/A/D) molecule, namely, propylenedioxythiophene–benzothiadiazole–propylenedioxythiophene, are investigated. The electrochemical and chemical oxidation
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::55f08b8f7e638d4629ed8410620f66dc
https://pubmed.ncbi.nlm.nih.gov/30950613
https://pubmed.ncbi.nlm.nih.gov/30950613
Publikováno v:
Organometallics. 35:2339-2347
We report here a series of emissive biphenyl cyclometalated gold(III) diethyl dithiocarbamate complexes having H, CF3, OMe, and tBu substitutions on the biphenyl moiety. Synthesis of these complexes was accomplished by a single-step reaction of the a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cbcb9c9f94f275c8c7784b9d7746713f
https://doi.org/10.1021/acs.organomet.6b00275
https://doi.org/10.1021/acs.organomet.6b00275