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The spiked-triangle cluster [Re2Pt(mu-H)(2)(CO)(9){HRe(CO)(5)}] (1), which contains a HRe(CO)(5) molecule bound to the Pt vertex of a Re2Pt triangle, reacts with methanolic NEt(4)OH to give the red anion [Re2Pt(mu-H)(2)(CO)(9){Re(CO)(5)}](-) (2), who
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od______1299::418264e2c801680aef7a13da3b40682d
http://hdl.handle.net/10281/32868
http://hdl.handle.net/10281/32868
The reaction of the unsaturated dinuclear molecule [Re2(mu-H)2(CO)8] with CS2 affords in good yield the complex [{Re2(mu-H)(CO)8}2(mu4-S2CH2)], containing a methanedithiolate H2CS2 fragment originated by the transfer of two hydrides, presumably one f
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od______1299::d479453ea209ef116b936485f528af32
http://hdl.handle.net/10281/32899
http://hdl.handle.net/10281/32899
The reaction of [Re2(mu-H)2(CO)8] with 1 equiv of Pt(COD)2 (COD = 1,5-cyclooctadiene) affords quantitatively the triangular cluster [Re2Pt(mu-H)2(CO)8(COD)], characterized spectroscopically and by X-ray analysis. The crystals are monoclinic, space gr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od______1299::5639d14828f4b9c4e940b8e5a8349518
http://hdl.handle.net/10281/32929
http://hdl.handle.net/10281/32929
The unsaturated molecule [Re2(mu-H)2(CO)8] adds [Ir(CO)4] - at -80-degrees-C to give the anion [(OC)4HRe-(mu-H) Re(CO)4Ir(CO)4]-, which at higher temperatures transforms into the triangular cluster [Re2IrH2-(CO)11] -; the latter, by reductive couplin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od______1299::d4c99a6b79cdf1f99a5e8b88c3210c19
http://hdl.handle.net/10281/32927
http://hdl.handle.net/10281/32927
Autor:
Beringhelli, T, Ceriotti, A, Dalfonso, G, Ciani, G, Sironi, A., DELLA PERGOLA, ROBERTO, MORET, MASSIMO
The reaction between [Re2(mu-H)2(CO)8] and [Pt(PPh3)2(C2H4)] at 273 K results in the insertion of the [Pt(PPh3)2] fragment into a Re(mu-H)Re bond, giving the triangular cluster [Re2Pt(mu-H)2(CO)8(PPh3)2], characterized spectroscopically. On increasin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od______1299::4f469c7ccb10e177b579d74353b28541
http://hdl.handle.net/10281/35206
http://hdl.handle.net/10281/35206
The reaction of the unsaturated anion [Re3(mu-H)4(CO)9(NCMe)]- with cyclohexylisocyanide gives the novel unsaturated anion [Re3(mu-H)4(CO)9(CNC6H11)]-. By reaction of this species with dimethylphenylphosphine a saturated compound is obtained, [Re3(mu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od______1299::5cc7d7b8587e10d531aad9ecb7543515
http://hdl.handle.net/10281/32949
http://hdl.handle.net/10281/32949
Different routes to the new family of cluster compounds [Re3(μ-H)3(CO)12-n(NCMe)n] (n = 1-3), containing substitution labile nitrile ligands, are described. The interconversions within the members of the family have been investigated and the stepwis
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od______1299::caabec1c0bb7b47cdf42d654ec3c69bc
http://hdl.handle.net/10281/32970
http://hdl.handle.net/10281/32970
Publikováno v:
ResearcherID
The hydrido complex HRe(CO)2(PPh3)3 reacts with tertiary amines, in the presence of O2 and H2O, to give Re(CO)2(PPh3)2(O2CR), containing a chelating carboxylato group originated by oxidation of the alkyl group of the amine. NEt3, N(n-Pr)3 and N(n-Bu)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::d6ddaa61ff281e4f08fcfc13e8a32707
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:A1992KN73500007&KeyUID=WOS:A1992KN73500007
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:A1992KN73500007&KeyUID=WOS:A1992KN73500007
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