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Akademický článek
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Autor:
P. Santini, Robert Bewley, R. S. Eccleston, C.H. Gardiner, B.D. Rainford, S.J.S. Lister, Andrew T. Boothroyd, L.D. Noailles, D.B. Currie
Publikováno v:
Physical Review Letters. 86:2082-2085
Neutron spectroscopic measurements of the magnetic excitations in PrO2 reveal (1) sharp peaks characteristic of transitions between levels of the 4f(1) configuration of Pr4+ split by the cubic crystal field, and (2) broad bands of scattering centered
Publikováno v:
Journal of Materials Chemistry. 9:283-287
The application of high pressures to synthesis in inorganic materials chemistry significantly widens the range and type of compound that can be prepared. Three different high pressure systems that allow, respectively, synthesis under flowing oxygen,
Autor:
Mark T. Weller, D.B. Currie
Publikováno v:
Physica C: Superconductivity. 297:95-102
The system Ln2Ba4Cu7−xNixO14+δ (247), Ln=lanthanide, yttrium, has been investigated by powder X-ray and neutron diffraction, thermogravimetric analysis and magnetic susceptibility measurements. Extended X-ray absorption fine structure (EXAFS) expe
Publikováno v:
Journal of Materials Chemistry. 7:1871-1875
The pale-yellow LiMFeIO 6 (M=K, Rb or Cs) have been prepared by reaction of MIO 4 , Li + and [Fe(H 2 O) 6 ] 3+ in hot aqueous solution at pH 9. Olive-green LiMCoIO 6 were prepared from MIO 4 , Li + and [Co(H 2 O) 6 ] 2+ in hot alkaline solution using
Publikováno v:
Physica C: Superconductivity. 224:43-50
The crystal structure of Ln 2 Ba 4 Cu 7 O 14+δ (Ln=Y, lanthanide) is derived from alternate blocks of the LnBa 2 Cu 3 O 7- x (123) and LnBa 2 Cu 4 O 8 (124) structures thus incorporating structural regions of oxygen non-stoichiometry and fixed stoic
Publikováno v:
Journal of Solid State Chemistry. 109:134-144
An extensive range of compounds in the La[sub 1[minus]x]Sr[sub x]FeO[sub 3[minus][sigma]] (0 [le] x [le] 1, 0 [le] [sigma] [le] 0.5) system have been synthesized. When [sigma] [approximately] 0 the system is composed of three crystallographically dif
Autor:
P.A.J. de Groot, Ravi Kumar, D.B. Currie, Mark T. Weller, P.C. Lanchester, M. Oussena, R. Walia
Publikováno v:
Solid State Communications. 89:783-787
We present the results of experimental studies of magnetic hysteresis in YBa2Cu4O8 superconductor. The variation of magnetic critical current density with magnetic field and temperature is presented. The results are analyzed on the basis of Bean's cr
Publikováno v:
J. Chem. Soc., Dalton Trans.. :1483-1487
The dark red-purple nickel(IV) periodataes MNilO6(M = Na, K, Rb, Cs or NH4) have been prepared by peroxohexaoxodisulfate oxidation of mixtures of nickel(II) salts, MNO3 and periodate ions in hot aqueous solution. Powder X-ray diffraction studies show