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Publikováno v:
J. Chem. Soc., Dalton Trans.. :2323-2327
The title compound crystallises in the orthorhombic system. wrth unit-cell dimensions a= 9.183(1), b= 15.745(1), c= 6.730(1)A, space group Aba2, and Z= 8. Diffractometer data have been used to solve the structure, and least-squares refinement with 48
Autor:
D. Philip Jones, William P. Griffith
Publikováno v:
J. Chem. Soc., Dalton Trans.. :2526-2532
The vibrational spectra of normal and 2H-enriched carbonate perhydrates M2[CO3]·nH2O2(Na,n= 1.5; K, Rb, or Cs, n= 3; NH4n= 1) and those of the normal and 13C-enriched peroxodicarbonates M2[C2O6](M = Na, K, Rb, or Cs), normal and 13C-enriched Li2[CO4
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :20
The presence of a peroxocarbonate species, likely to be HCO4– in pH-dependent equilibrium with CO42–, in solutions of HCO3– in an excess of H2O2 is inferred from Raman and 13C n.m.r. spectroscopy; similar evidence is presented for the presence