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A Comparative Study of Photovoltaic Effects with Silver-Silver Halide Electrodes

Autor: D. Feakins, J. M. Clear, W. E. Waghorne, H. W. Sidebottom, J. Corish

Publikováno v: Berichte der Bunsengesellschaft für physikalische Chemie. 84:634-642

The photovoltaic effect produced by silver-silver halide electrodes in a cell of the type Ag | AgX(dark) | Electrolytic solution | AgX(illuminated) | Ag has been investigated under well-defined experimental conditions where X = Cl, Br, and I. The pri

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e070f804c91c070a7434945e0e768ecc
https://doi.org/10.1002/bbpc.19800840706

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The thermodynamics of solutions

Autor: W. E. Waghorne, J. J. Mullally, F. M. Canning, D. Feakins

Publikováno v: Pure and Applied Chemistry. 61:133-142

This paper explores the relationship between thermodynamics and two other types of investigation. Structure determinations by neutron diffraction and computer simulation give a clear picture of first-shell solvation for a number of cations in water.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3e17c561390828ef802b2241c6b9d229
https://doi.org/10.1351/pac198961020133

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Preferential solvation of ions and solvent transport

Autor: D. Feakins, R. O'Neill, E. Waghorne

Publikováno v: Pure and Applied Chemistry. 54:2317-2326

In the common binary aqueous mixtures, for example dioxan + water, an ion induces a non-random equilibrium distribution of solvent molecules such that close to the ion one solvent component is in excess of its concentration in the bulk. Thermodynamic

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1d8ea874138f153f9f60338ac22192f0
https://doi.org/10.1351/pac198254122317

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Structure and basicity. Part VII. Cyclotriphosphazatrienes containing amino-, chloro-, and phenyl-groups. New data: substituent constants for amino-groups and their application to the ‘saturation effect’ and to structure determination; pK′a,2and structure

Autor: R. A. Shaw, P. Watson, D. Feakins, S. N. Nabi

Publikováno v: J. Chem. Soc. A. :2468-2475

The basicities of certain cyclotriphosphazatrienes containing amino-, chloro-, and phenyl-groups in various combinations have been measured in nitrobenzene. The data are used in conjunction with those of earlier Parts of the Series to calculate subst

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::96c5455b2cf8b009887788da572536f4
https://doi.org/10.1039/j19690002468

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The relative viscosities of solutions of sodium and potassium chlorides and bromides in N-methylformamide at 25, 35, and 45°

Autor: D. Feakins, K. G. Lawrence

Publikováno v: J. Chem. Soc. A. :212-219

The relative viscosities of solutions of sodium and potassium chlorides and bromides in N-methylformamide have been determined at 25, 35, and 45°. Values of the coefficients A, B, and D in the extended Jones–Dole equation ηr= 1 +Ac½+Bc+Dc2, have

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c2300e4ea0a8de2e5267da884cc63acf
https://doi.org/10.1039/j19660000212

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Studies in ion solvation in non-aqueous solvents and their aqueous mixtures. Part V. The halogen acids in 10, 20, 40, and 60%(W/W) acetic acid–water mixtures at 25°

Autor: D. J. Turner, H. P. Bennetto, D. Feakins

Publikováno v: J. Chem. Soc. A. :1211-1216

Standard e.m.f.s. have been obtained for the cells H2|HX|AgX–Ag (X = Br or I) in 10, 20, 40, and 60%(W/W) solutions of acetic acid in water. Some measurements were made by a new rapid technique. Molar free energies of transfer, ΔGt°, from water t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::eb28a1d7dd7d2fbfc64b468abec9da99
https://doi.org/10.1039/j19660001211

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Studies in ion solvation in non-aqueous solvents and their aqueous mixtures. Part X. Free energies of transfer of the alkali-metal chlorides from water to a 20%(w/w) dioxan–water mixture at 25°. Amalgam electrodes and the digital voltmeter

Autor: D. Feakins, H. P. Bennetto, K. G. Lawrence

Publikováno v: J. Chem. Soc. A. :1493-1499

E.m.f. measurements on the double cell Ag–AgCl|MCl(m8),S|M(Hg)|MCl(mw),W|AgCl–Ag, where S is a 20%(w/w) dioxan–water mixture, and W is water, are reported for the alkali-metal chlorides MCl. The measurements were greatly facilitated by the use

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d5687c962653f0e2d183f16aae92d401
https://doi.org/10.1039/j19680001493

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Studies in ion solvation in non-aqueous solvents and their aqueous mixtures. Part VI. The solubility product of silver chloride in 10 and 43·12% methanol–water mixtures, and a comparison of Ag+with d° cations

Autor: K. G. Lawrence, R. P. T. Tomkins, D. Feakins

Publikováno v: J. Chem. Soc. A. :753-757

The thermodynamic solubility product of silver chloride at 25° has been obtained, by e.m.f. measurements, in 10 and 43·12%(w/w) methanol–water mixtures, and its free energies of transfer from water to these mixtures calculated. If computations of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d0c0c78af537e5f5778853a0d99455bd
https://doi.org/10.1039/j19670000753

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