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n-Participation in Solvolysis and Secondary Deuterium Isotope Effects. Octahydrodimethanonaphthalene System

Autor: R. Malojčić, S. Borčić, D. E. Sunko

Publikováno v: Croatica Chemica Acta
Volume 49
Issue 4

Specifically deuterated brosylates of unsaturated carbinols with endo-, exo-fused norbornanes structure 4-0H were prepared and their acetolysis rates measured at 25.0 °c. A secondary a-deuterium isotope effect of kH/kn = 1.20 was obtained which is c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od_______951::9f26ccca8f5f6bc019e784bb6479d874
https://hrcak.srce.hr/file/289161

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5-Methoxyl Participation in Solvolysis and Secondary Deuterium Isotope Effects

Autor: R. Eliason, S. Borčić, D. E. Sunko

Publikováno v: Croatica Chemica Acta
Volume 51
Issue 3

Specifically deuterated 4-methoxy-1-pentyl broij'ylates (IP- 1,1-d2, IP-2,2-d2) and 5-methoxy-2-pentyl brosylates (IS-2-d, 1S- -1 ,1,1 - d3, 1S-OCD3) were prepared, their solvolysis rates measured in 950/o ethanol and the corresponding kinetic second

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od_______951::f9d1cdaa7d264ee791d3a0674da40d5f
https://hrcak.srce.hr/195945

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