Zobrazeno 1 - 10
of 61
pro vyhledávání: '"D. E. Sullivan"'
Publikováno v:
Tetrahedron Letters. 54:1612-1615
An efficient strategy for the construction of C13-oxidized cembrenolides is reported. Central to this strategy is the installation of the C13 hydroxyl group prior to cembrane macrocyclization (via formation of the C1–C2 bond), allowing access to bo
Publikováno v:
Macromolecules. 40:1187-1195
On the basis of a mean-field treatment of semiflexible polymer chains, we analyze the structure of long wormlike polymers sterically confined between two parallel, structureless walls separated by a distance W. With the Onsager excluded-volume intera
Autor:
D. E. Sullivan, Jeff Z. Y. Chen
Publikováno v:
Macromolecules. 39:7769-7773
We consider a wormlike polymer confined between two flat surfaces separated by a distance W. Using a wormlike chain formalism that couples the orientational and positional degrees of freedom, for a wormlike chain much longer than the persistence leng
Publikováno v:
Europhysics Letters (EPL). 72:89-95
We analyze the structure and phase behavior of long wormlike polymers sterically confined between two parallel, structureless walls, separated by a distance W. We focus on the case where W is comparable to the persistence length lp of the polymers, W
Autor:
D. E. Sullivan, Dominik Düchs
Publikováno v:
Journal of Physics: Condensed Matter. 14:12189-12202
We present a self-consistent field theory (SCFT) of semiflexible (wormlike) diblock copolymers, each consisting of a rigid and a flexible part. The segments of the polymers are otherwise identical, in particular with regard to their interactions, whi
Publikováno v:
The Journal of Chemical Physics. 114:3314-3324
A density-functional theory of the isotropic–nematic phase transition in both rigid and semiflexible hard-sphere chain fluids is described. The theory is based on an exact analytical evaluation of the excluded volume and second virial coefficient B
Publikováno v:
Physical Review E. 62:3708-3718
Department of Physics and Guelph-Waterloo Physics Institute, University of Guelph, Guelph, Ontario, Canada N1G 2W1~Received 1 February 2000!The smectic-A phase boundaries of a hard-spherocylinder fluid are calculated using a density-functionaltheory
Autor:
D. E. Sullivan, A. N. Shalaginov
Publikováno v:
Physical Review E. 62:699-710
We present a theoretical study of the dynamic displacement-displacement and intensity-intensity (for coherent soft x-ray scattering) correlations in Sm-A as well as Cr-B free-standing films. The work is based on a continuous hydrodynamic model that a
Publikováno v:
The Journal of Chemical Physics. 110:11630-11642
We present a modification of the generalized Flory dimer theory to investigate the nematic (N) to isotropic (I) phase transition in chain fluids. We focus on rigid linear fused hard-sphere (LFHS) chain molecules in this study. A generalized density f
Autor:
Apichart Linhananta, D. E. Sullivan
Publikováno v:
Physical Review E. 57:4547-4557