Zobrazeno 1 - 6
of 6
pro vyhledávání: '"D. C. Warrell"'
Publikováno v:
Journal of Radioanalytical Chemistry. 64:41-45
The development of tritium nuclear magnetic resonance spectroscopy now makes it possible to determine the tritium distribution in virtually any organic compound at the millicurie level of radioactivity. Results of catalytic experiments show that in s
Publikováno v:
Journal of Steroid Biochemistry. 9:818
Publikováno v:
Journal of the Chemical Society C: Organic. :1693
When treated with concentrated aqueous sodium hydroxide, 2-chlorotropone yields only benzoic acid. With more dilute alkali, salicylaldehyde (up to 40%) is also formed. 2-Bromo- and 2-iodo-tropone behave similarly. Deuteriation studies have shown that
Publikováno v:
Journal of the Chemical Society C: Organic. :1969
Using a variety of oxidising agents, nitro-2-chlorotropones are converted into m-hydroxybenzaldehydes in which all the substituents of the original tropone are retained. Thus, 2-chloro-7-nitrotropone gives 4-chloro-3-hydroxy-2-nitrobenzaldehyde, and
Autor:
D. C. Warrell, R. C. Cookson
Publikováno v:
Journal of the Chemical Society C: Organic. :1391
Sulphuric acid rearranges 5-aryl-1,4-dimethyl-2,3-diphenylbicyclo[2,2,1]hepten-7-ones into 6-aryl-1,3-dimethyl-4,5-diphenylbicyclo[3,2,0]hept-3-en-2-ones. Since the pure endo-(V) or exo-[2,2,1]-isomer (VI) gives a mixture of exo-(VII) and endo-[3,2,0
Autor:
D. C. Warrell, E. J. Forbes
Publikováno v:
Journal of the Chemical Society C: Organic. :1964
When treated with nitric acid in acetic acid 2-chlorotropone gave 2-chloro-7-nitrotropone as the major product. In addition, 2-chloro-4,6-dinitrophenol and two m-hydroxybenzaldehydes were obtained together with picric acid and 2,5-dinitrobenzoic acid