Zobrazeno 1 - 10
of 21
pro vyhledávání: '"D. C. TIMM"'
Autor:
D. J. Robbins, D. C. Timm
Publikováno v:
Macromolecules. 31:4319-4334
Purely deterministic derivations are reported regarding the internal, network chain structure that contributes to rubber elasticity in polymerizations of A2−A2+B2 monomers. The A2−A2 monomer originally contained two primary sites. Upon reaction,
Publikováno v:
Industrial & Engineering Chemistry Research. 36:1360-1372
Subject to intermolecular addition and intramolecular cross-linking reactions, deterministic models which describe chain infrastructure for a random A4 + B2 resin and a Poisson-type, chain-initiated epoxy anhydride thermoset were derived. Sol fractio
Publikováno v:
Macromolecules. 28:8729-8734
A procedure for the analyses of nonisothermal, batch reaction data is presented. Nonlinear regression analyses based on a least-squares objective function yield kinetic rate expression parameters from a single experiment. Data collected for the therm
Autor:
D. C. Timm, R. Tadros
Publikováno v:
Macromolecules. 28:7441-7446
A linear-chained epoxy resin was formulated from phenyl glycidyl ether and nadic methyl anhydride catalyzed by benzyldimethylamine. Intermolecular polymerizations were modeled as a parallel set of propagation reactions. Fourier-transform infrared spe
Publikováno v:
Journal of Intelligent Material Systems and Structures. 6:436-442
Smart materials or structures have embedded sensors to monitor their own state as well as environmental stimuli. A novel sensor was developed by sputtering a piezoelectric film onto a conductive fiber or metal wire. This sensor, similar in configurat
Publikováno v:
Macromolecules. 26:1369-1375
Intermolecular reactions for a thermoplastic, epoxy resin cured with an anhydride hardener and catalyzed by a tertiary amine were studied extensively at the molecular level. The reaction mechanism described by Antoon and Koenig was condensed to two r
Autor:
D. C. Timm, J. F. Scamehorn
Publikováno v:
Journal of Polymer Science: Polymer Chemistry Edition. 13:1241-1251
A theoretical description of chain-growth polymerization is presented in terms of a distributed parameter model. Analysis of molecular distributions of macromolecular materials results in graphical procedures capable of yielding absolute values for k
Publikováno v:
AIChE Journal. 20:43-50
An experimental procedure based on continuous crystal seeding was developed which can explicitly determine the fundamental relationship between collision breeding and the leading moments of the crystal size distribution. For the aqueous, cooling crys
Publikováno v:
Polymer Engineering and Science. 24:930-935
Structure moleculaire de resines thermodurcissables durcies seules ou renforcees de Kevlar 49 par analyse des extraits de resine par chromatographie par permeation de gel
Autor:
D. C. Timm, John W. Rachow
Publikováno v:
Journal of Polymer Science: Polymer Chemistry Edition. 13:1401-1416
Gel-permeation chromatography is an excellent tool for obtaining polymer fractionation data. Inasmuch as chromatograms are functions of instrument operating conditions, an interpretation procedure must be employed to yield correct molecular distribut