Zobrazeno 1 - 10
of 131
pro vyhledávání: '"D. N. Reinhoudt"'
Autor:
C. G. Kouwenhoven, D. N. Reinhoudt
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 95:67-73
Two possible routes have been investigated for the synthesis of 1-heterocycloheptatrienes starting from annulated cyclobutene derivatives. The first approach comprised a [2 + 2 + 2] cycloreversion of tetracyclic compounds prepared from 2,3-bis(methox
Autor:
D. N. Reinhoudt, C. G. Kouwenhoven
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 93:129-132
A 1-benzoxepin has been synthesized in high yield by cycloaddition of 3-pyrrolidinobenzofuran to dimethyl acetylenedicarboxylate, followed by thermal rearrangement of the [2 + 2] cyclo-adduct. A kinetic study of the isomerization revealed that the ri
Autor:
D. N. Reinhoudt, C. G. Kouwenhoven
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 92:865-878
A general method has been developed for the synthesis of two novel classes of heterocyclic compounds, 2,3-(or 2,7)-dihydrothiepins and 2,3-dihydro-8H-thiocins. It comprises the cycloaddition of enamine derivatives of tetrahydro-thiophen-3-ones or 4-t
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 100:453-459
A number of non-ionic compounds have been found to form solid complexes with 18-crown-6. The highest efficiencies of isolation and the highest selectivities were obtained with nitromethane, dimethyl carbonate and dimethyl oxalate. The usefulness of t
Autor:
D. N. Reinhoudt
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 101:277-287
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 92:819-825
The racemization-free synthesis of N-phthaloyl amino acids (Pht-amino acids) from amino acid esters, by using o-methoxycarbonylbenzoyl chloride in anhydrous media, is described. The N-phthaloyl amino acids and esters from proteins were obtained in hi
Autor:
C. G. Kouwenhoven, D. N. Reinhoudt
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 93:321-324
The enamine-like character of a pyrrolidino-substituted carbon-carbon double bond in heteroaromatics has been demonstrated by the fact that such compounds can undergo cycloaddition reactions with 1,3-dipolar reagents such as benzonitrile oxides, diar
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 102:164-173
The use of seawater as injection fluid in oil-producing formations often leads to blocking of the wells as a result of barium sulfate-scale formation. Macrocyclic complexants specifically designed to solubilize barium sulfate efficiently into water h
Autor:
D. N. Reinhoudt, H. C. Mutreja
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 99:241-246
Ketenes react with 1-pyrrolidinyl-substituted heteroaromatics 3-5 to give 2-acyl derivatives 10, 13, 16-18 and 20 and, in some cases 2: 1 reaction products 11 and 12. The latter products can be attributed to reaction of 1,4-dipolar intermediates with
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 100:449-452
A safe, efficient and selective method has been developed for the isolation and purification of crown ethers to replace the conventional procedure, which involves repeated vacuum distillations and has reportedly led to destructive explosions. The met