Zobrazeno 1 - 6
of 6
pro vyhledávání: '"D S Zakharova"'
Publikováno v:
Тонкие химические технологии, Vol 11, Iss 2, Pp 57-65 (2016)
The catalytic system Pd (OAc)2-HClO4--CH3CN (AN)-H2O of olefins oxidation was studied. Information about the ways of forming catalytic active cationic palladium complexes was detected. Analysis of the electron spectroscopy data shows the probability
Externí odkaz:
https://doaj.org/article/d1db0997d6ec4c309e94099c5db153b6
Autor:
D. S. Zakharova, A. N. Semenyako, O. A. Chertkova, A. V. Frolkova, E. A. Katsman, L. G. Bruk, O. N. Temkin
Publikováno v:
Тонкие химические технологии, Vol 10, Iss 3, Pp 77-84 (2015)
During the study of cyclohexene oxidation by p-benzoquinones into cyclohexanone in water-organic solutions of cationic complexes of palladium(II) it was demonstrated that the initial reaction rate R0 depends complicatedly on water molar fraction for
Externí odkaz:
https://doaj.org/article/8c787594342c45eab9490f75f5301abb
Publikováno v:
METALLOFIZIKA I NOVEISHIE TEKHNOLOGII. 42:1303-1313
Publikováno v:
Proceedings of the International Scientific Conference "Far East Con" (ISCFEC 2020).
Autor:
I. V. Petrov, O. N. Temkin, O. Yu. Istomina, E. A. Katsman, K. Yu. Odintsov, D. S. Zakharova, L. G. Bruk
Publikováno v:
Kinetics and Catalysis. 51:691-703
A kinetic study of cyclohexene oxidation by p-quinones in water-acetonitrile solutions of cationic Pd(II) complexes has been carried out for the first time. The observed kinetic regularities (dependence of the initial rate on the HClO4 and p-benzoqui
Publikováno v:
Russian Chemical Bulletin. 62:844-846
Kinetic isotope effects for oxidation reactions of ethylene and cyclohexene in solutions of cationic palladium(ii) complexes in MeCN-H2O(D2O) systems, were measured. It was established that the ratio of the initial reaction rates \({{R_0^{H_2 O} } \m