Výsledky vyhledávání

Akademický článek

Synthesis and Characterization of Super Bulky β-Diketiminato Group 1 Metal Complexes

Autor: Dafydd D. L. Jones, Samuel Watts, Cameron Jones

Publikováno v: Inorganics, Vol 9, Iss 9, p 72 (2021)

Sterically bulky β-diketiminate (or Nacnac) ligand systems have recently shown the ability to kinetically stabilize highly reactive low-oxidation state main group complexes. Metal halide precursors to such systems can be formed via salt metathesis r

Externí odkaz: https://doaj.org/article/eb8d9a61ccc846a0b0ea3b4cd42599b2

Zobrazit plný text záznamu

Plný text ve formátu HTML

Akademický článek

Thresholds of biodiversity and ecosystem function in a forest ecosystem undergoing dieback

Autor: P. M. Evans, A. C. Newton, E. Cantarello, P. Martin, N. Sanderson, D. L. Jones, N. Barsoum, J. E. Cottrell, S. W. A’Hara, L. Fuller

Publikováno v: Scientific Reports, Vol 7, Iss 1, Pp 1-9 (2017)

Abstract Ecological thresholds, which represent points of rapid change in ecological properties, are of major scientific and societal concern. However, very little research has focused on empirically testing the occurrence of thresholds in temperate

Externí odkaz: https://doaj.org/article/07d466a20f9a4ae59e590b202be94018

Zobrazit plný text záznamu

Plný text ve formátu HTML

The septate junction component Bark beetle is required forDrosophilaintestinal barrier function and homeostasis

Autor: R. A. Hodge, M. Ghannam, E. Edmond, F. de la Torre, Cecilia D’Alterio, N.H. Kaya, M. Resnik-Docampo, T. Reiff, D. L. Jones

Age-related loss of intestinal barrier function has been found across species, and the causes remain unknown. The intestinal epithelial barrier is maintained by tight junctions (TJs) in mammals and septate junctions (SJs) in insects. Specialized tric

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c56e4dec38ac9721a72fe30164045f1e
https://doi.org/10.1101/2022.11.07.515432

Zobrazit plný text záznamu

Photochemically Activated Dimagnesium(I) Compounds: Reagents for the Reduction and Selective C−H Bond Activation of Inert Arenes

Autor: Laurent Maron, Cameron Jones, Iskander Douair, Dafydd D. L. Jones

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2021, 60 (13), pp.7087-7092. ⟨10.1002/anie.202017126⟩

International audience; The photochemical activation of dimagnesium(I) compounds, and subsequent high yielding, regioselective reactions with inert arenes are reported. Irradiating benzene solutions of [{((Ar)Nacnac)Mg}(2)] ((Ar)Nacnac=[HC(MeCNAr)(2)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::97a731acbb255243ce0d022132fdfb34
https://doi.org/10.1002/ange.202017126

Zobrazit plný text záznamu

Plný text ve formátu HTML

Characterisation of riverine dissolved organic matter using a complementary suite of chromatographic and mass spectrometric methods

Autor: C. E. M. Lloyd, L. A. Mena-Rivera, J. A. Pemberton, P. J. Johnes, D. L. Jones, C. A. Yates, F. L. Brailsford, H. C. Glanville, C. A. McIntyre, R. P. Evershed

Publikováno v: Lloyd, C E M, Mena Rivera, L A, Pemberton, J, Johnes, P J, Jones, D, Yates, C A, Brailsford, F L, Glanville, H C, McIntyre, C A & Evershed, R P 2022, ' Characterisation of riverine dissolved organic matter using a complementary suite of chromatographic and mass spectrometric methods ', Biogeochemistry . https://doi.org/10.1007/s10533-022-00913-z

Dissolved organic matter (DOM) plays a fundamental role in nutrient cycling dynamics in riverine systems. Recent research has confirmed that the concentration of riverine DOM is not the only factor regulating its functional significance; the need to

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::303c859a652f96596b28c7d16d11bb0f
https://eprints.keele.ac.uk/10779/1/Lloyd2022_Article_CharacterisationOfRiverineDiss.pdf

Zobrazit plný text záznamu

Sterically controlled reductive oligomerisations of CO by activated magnesium(i) compounds: deltate vs. ethenediolate formation

Autor: Laurent Maron, Dafydd D. L. Jones, Cameron Jones, K. Yuvaraj, Iskander Douair

Publikováno v: Chemical Science
Chemical Science, 2020, 11 (13), pp.3516-3522. ⟨10.1039/d0sc00836b⟩

An extremely bulky, symmetrical three-coordinate magnesium(i) complex, [{(TCHPNacnac)Mg}2] (TCHPNacnac = [{(TCHP)NCMe}2CH]−, TCHP = 2,4,6-tricyclohexylphenyl) has been prepared and shown to have an extremely long Mg–Mg bond (3.021(1) Å) for such

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c9ec082fc78b98a2d796ccf081c36dbb
https://doi.org/10.1039/d0sc00836b

Zobrazit plný text záznamu

Reduction of tert-butylphosphaalkyne and trimethylsilylnitrile with magnesium(i) dimers

Autor: Daniel W. N. Wilson, Dafydd D. L. Jones, Cory D. Smith, Meera Mehta, Cameron Jones, Jose M. Goicoechea

Publikováno v: Wilson, D W N, Jones, D D L, Smith, C D, Mehta, M, Jones, C & Goicoechea, J M 2022, ' Reduction of tert-butylphosphaalkyne and trimethylsilylnitrile with magnesium(i) dimers ', Dalton Transactions, vol. 51, pp. 898-903 . https://doi.org/10.1039/D1DT03990C

We report on the reactivity of magnesium(I) dimers, [Mg(nacnac)]2 (nacnac = HC[C(Me)N(2,6-iPr2C6H3)]2 ([DippLMg]2) and HC[C(Me)N(2,4,6-Me3C6H2)]2 ([MesLMg]2)), towards the phosphaalkyne tBuCP. The steric profile of the magnesium(I) dimer results in s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2fd484787a4974796dca0664480f4bdc
https://pure.manchester.ac.uk/ws/files/212044218/Magnesium_manuscript_no_highlights.docx

Zobrazit plný text záznamu