Symmetrical and Unsymmetrical Dicopper Complexes Based on Bis-Oxazoline Units: Synthesis, Spectroscopic Properties and Reactivity

Autor: James A. Isaac, Gisèle Gellon, Florian Molton, Christian Philouze, Nicolas Le Poul, Catherine Belle, Aurore Thibon-Pourret

Publikováno v: Inorganics, Vol 11, Iss 8, p 332 (2023)

Copper–oxygen adducts are known for being key active species for the oxidation of C–H bonds in copper enzymes and their synthetic models. In this work, the synthesis and spectroscopic characterizations of such intermediates using dinucleating lig

Externí odkaz: https://doaj.org/article/820753359b8043ca9bcf184e6f2b89d3

High-valence CuIICuIII species in action: demonstration of aliphatic C–H bond activation at room temperature

Autor: Christian Philouze, Amélie Durand, Aurore Thibon-Pourret, Nicolas Le Poul, Catherine Belle, James A. Isaac

Publikováno v: Chemical Communications
Chemical Communications, Royal Society of Chemistry, 2019, 55 (84), pp.12711-12714. ⟨10.1039/C9CC04422A⟩
Chemical Communications, Royal Society of Chemistry, 2019, 55 (84), pp.12711-12714. ⟨10.1039/c9cc04422a⟩

International audience; The electrochemically generated CuIICuIII mixed-valence species promotes activation of strong aliphatic C–H bonds (i.e. toluene) at room temperature. The mechanistic pathway turns from stoichiometric to catalytic upon additi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e168751ded1675cc2962ae034e7ffdf0
https://doi.org/10.1039/c9cc04422a